Effect of lattice structure of silicon carbide on crystal formation of carbide-derived carbon

Min Gun Jeong, Seo Hyun Yoon, Yoon Soo Chun, Eung Seok Lee, Dae Soon Lim

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)


Nanostructured carbide-derived carbons (CDCs) were synthesized from hexagonal SiC (α-SiC) and cubic SiC (β-SiC) powders via chlorination at temperatures between 900 and 1200 °C. The content of the sp2-and sp3-bonded carbon phases and their crystallinity were analyzed by Raman spectroscopy. The nanocrystalline phases of the synthesized CDCs were observed and characterized by transmission electron microscopy and electron energy-loss spectroscopy. The morphology of CDCs showed interesting features that varied with the starting SiC powder. Diamond nanocrystals were more frequently observed in α-SiC-derived carbons than in β-SiC-derived carbons, and the rate of graphitization was affected by the SiC polytype, synthesis temperature and hydrogen content. A possible mechanism responsible for the observed results was also investigated.

Original languageEnglish
Pages (from-to)19-27
Number of pages9
Issue number1
Publication statusPublished - 2014

Bibliographical note

Funding Information:
This work was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Commerce, Industry and Energy , Republic of Korea.

Publisher Copyright:
© 2014 Elsevier Ltd. All rights reserved.

Copyright 2017 Elsevier B.V., All rights reserved.

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science


Dive into the research topics of 'Effect of lattice structure of silicon carbide on crystal formation of carbide-derived carbon'. Together they form a unique fingerprint.

Cite this