Effect of PEDOT:PSS-molecule interface on the charge transport characteristics of the large-area molecular electronic junctions

Gunuk Wang, Seok In Na, Tae Wook Kim, Yonghun Kim, Sungjun Park, Takhee Lee

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)


We have studied the effect of the PEDOT:PSS-molecule contact on the electrical characteristics of molecular junctions consisting of N-alkanedithiol and naphthalenethiol molecules. In this study, we experimentally investigated the properties of PEDOT:PSS-interlayer molecular junctions as they depended on the two kinds of PEDOT:PSS films (the pure PEDOT:PSS film and the dimethyl sulfoxide (DMSO)-modified PEDOT:PSS film) and their thermal annealing treatment. We observed that the electrical properties of these molecular junctions are influenced by the morphology and conductivity of the PEDOT:PSS films and by the thermal treatment. In particular, the resistance of the PEDOT:PSS-interlayer molecular junctions depended on the kind of PEDOT:PSS film and the temperature, within the range of elevated temperatures (higher than room temperature) tested. These experimental results are explained by the change of the interfacial properties of the PEDOT:PSS-molecule contact, which are influenced by the morphology change of the PEDOT:PSS film and the removal of residual DMSO or water from the interface.

Original languageEnglish
Pages (from-to)771-777
Number of pages7
JournalOrganic Electronics
Issue number5
Publication statusPublished - 2012 May
Externally publishedYes

Bibliographical note

Funding Information:
This work was supported by the National Research Laboratory ; a Korean National Core Research Center grant of the Korean Ministry of Education, Science, and Technology ; the Korea Institute of Science and Technology Institutional Program ; and Research Settlement Fund for the new faculty of Seoul National University .


  • Molecular electronic devices
  • Molecular interface

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • General Chemistry
  • Condensed Matter Physics
  • Materials Chemistry
  • Electrical and Electronic Engineering


Dive into the research topics of 'Effect of PEDOT:PSS-molecule interface on the charge transport characteristics of the large-area molecular electronic junctions'. Together they form a unique fingerprint.

Cite this