Effect of sub-T_gannealing on the corrosion resistance of the Cu-Zr amorphous alloys

Despite the economy of material cost and excellent toughness of Cu-based amorphous alloys, especially Cu₅₀Zr₅₀, their poor corrosion resistance to a chloride medium limits their widespread applications. In this study, corrosion tests were performed on the Cu₅₀Zr₅₀amorphous alloy with different degrees of short-range order, which were prepared by annealing below the glass transition temperature (T_g). It was found that the corrosion resistance of amorphous alloys is improved to a significant level when the alloys were heated below T_g. Calorimetric studies showed that thermally activated relaxation process of created disorder, which occurs during sub-T_gannealing, is responsible for the improvement in the corrosion resistance. Molecular dynamics simulations performed on the Cu-Zr amorphous alloys demonstrated that the relaxation process of the alloys is associated with the formation of energetically stable icosahedra and icosahedron-like structures. Our study highlights the effects of sub-T_gannealing on the improvement in the corrosion resistance of the amorphous alloys from the viewpoint the relaxation process of the short-range orders.