Effect of ultraviolet-ozone on ITO/P3HT interface for PEDOT:PSS-free polymer solar cells

  • Wan Jae Dong
  • , Gwan Ho Jung
  • , Soo Young Kim
  • , Jong Lam Lee*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A simple device structure of bulk hetero-junction polymer solar cells (PSCs) with poly(3-hexylthiophene) and phenyl-C61-butyric acid methyl ester (P3HT:PCBM) is demonstrated without poly(3,4-ethylenedioxythiophene): poly(styrene-sulfonate) (PEDOT:PSS). Ultraviolet (UV)-ozone treatment alters the surface atomic compositions making it oxygen rich and carbon deficient. These chemical changes increase the workfunction of indium tin oxide (ITO) by 0.2 eV. The ITO anode with high workfunction results in efficient hole collection at ITO/P3HT interface. This method makes it possible to eliminate PEDOT:PSS with high efficiency of 3.35%, identical to the device with PEDOT:PSS (3.35%). In addition, the PSC with UV-ozone treated ITO anode shows 3.6 times longer life-time than that with PEDOT:PSS.

Original languageEnglish
Pages (from-to)240-245
Number of pages6
JournalSolar Energy Materials and Solar Cells
Volume109
DOIs
Publication statusPublished - 2013
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Hole extraction layer
  • Interface
  • PEDOT:PSS
  • Polymer solar cells
  • UV-ozone

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films

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