Effects of photon recycling and scattering in high-performance perovskite solar cells

Changsoon Cho; Yeoun Woo Jang; Seungmin Lee; Yana Vaynzof; Mansoo Choi; Jun Hong Noh; Karl Leo

doi:10.1126/sciadv.abj1363

Effects of photon recycling and scattering in high-performance perovskite solar cells

Changsoon Cho, Yeoun Woo Jang, Seungmin Lee, Yana Vaynzof, Mansoo Choi, Jun Hong Noh, Karl Leo

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Efficient external radiation is essential for solar cells to achieve high power conversion efficiency (PCE). The classical limit of 1/2n2 (n, refractive index) for electroluminescence quantum efficiency (ELQE) has recently been approached by perovskite solar cells (PSCs). Photon recycling (PR) and light scattering can provide an opportunity to surpass this limit. We investigate the role of PR and scattering in practical device operation using a radiative PSC with an ELQE (13.7% at 1 sun) that significantly surpasses the classical limit (7.4%). We experimentally analyze the contributions of PR and scattering to this strong radiation. A novel optical model reveals an increase of 39 mV in the voltage of our PSC. This analysis can provide design principles for future PSCs to approach the Shockley-Queisser efficiency limit.

Original language	English
Article number	eabj1363
Journal	Science Advances
Volume	7
Issue number	52
DOIs	https://doi.org/10.1126/sciadv.abj1363
Publication status	Published - 2021 Dec

Bibliographical note

Funding Information:
This study was funded by the Alexander von Humboldt Foundation via Humboldt Research Fellowship for Postdoc Researchers (C.C.), Global Frontier R&D Program of the Center for Multiscale Energy Systems funded by the Korean government (MSIP) (NRF- 2012M3A6A7054855) (Y.-W.J. and M.C.), National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2020R1A2C3009115) (S.L. and J.H.N.), Deutsche Forschungsgemeinschaft (DFG) for funding in the framework of SPP 2196 (project PERFECT PVs, VA 991/3-1 and DE 830/22-1) (Y.V.), and DFG for funding in project Le747/64-1 (K.L.).

Funding Information:
Acknowledgments Funding: This study was funded by the Alexander von Humboldt Foundation via Humboldt

Publisher Copyright:
Copyright © 2021 The Authors, some rights reserved.

ASJC Scopus subject areas

General

Access to Document

10.1126/sciadv.abj1363

Cite this

@article{65d2b14c6e4543deac66b92569958c5b,

title = "Effects of photon recycling and scattering in high-performance perovskite solar cells",

abstract = "Efficient external radiation is essential for solar cells to achieve high power conversion efficiency (PCE). The classical limit of 1/2n2 (n, refractive index) for electroluminescence quantum efficiency (ELQE) has recently been approached by perovskite solar cells (PSCs). Photon recycling (PR) and light scattering can provide an opportunity to surpass this limit. We investigate the role of PR and scattering in practical device operation using a radiative PSC with an ELQE (13.7% at 1 sun) that significantly surpasses the classical limit (7.4%). We experimentally analyze the contributions of PR and scattering to this strong radiation. A novel optical model reveals an increase of 39 mV in the voltage of our PSC. This analysis can provide design principles for future PSCs to approach the Shockley-Queisser efficiency limit.",

author = "Changsoon Cho and Jang, {Yeoun Woo} and Seungmin Lee and Yana Vaynzof and Mansoo Choi and Noh, {Jun Hong} and Karl Leo",

note = "Funding Information: This study was funded by the Alexander von Humboldt Foundation via Humboldt Research Fellowship for Postdoc Researchers (C.C.), Global Frontier R&D Program of the Center for Multiscale Energy Systems funded by the Korean government (MSIP) (NRF- 2012M3A6A7054855) (Y.-W.J. and M.C.), National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2020R1A2C3009115) (S.L. and J.H.N.), Deutsche Forschungsgemeinschaft (DFG) for funding in the framework of SPP 2196 (project PERFECT PVs, VA 991/3-1 and DE 830/22-1) (Y.V.), and DFG for funding in project Le747/64-1 (K.L.). Funding Information: Acknowledgments Funding: This study was funded by the Alexander von Humboldt Foundation via Humboldt Publisher Copyright: Copyright {\textcopyright} 2021 The Authors, some rights reserved.",

year = "2021",

month = dec,

doi = "10.1126/sciadv.abj1363",

language = "English",

volume = "7",

journal = "Science Advances",

issn = "2375-2548",

publisher = "American Association for the Advancement of Science",

number = "52",

}

TY - JOUR

T1 - Effects of photon recycling and scattering in high-performance perovskite solar cells

AU - Cho, Changsoon

AU - Jang, Yeoun Woo

AU - Lee, Seungmin

AU - Vaynzof, Yana

AU - Choi, Mansoo

AU - Noh, Jun Hong

AU - Leo, Karl

N1 - Funding Information: This study was funded by the Alexander von Humboldt Foundation via Humboldt Research Fellowship for Postdoc Researchers (C.C.), Global Frontier R&D Program of the Center for Multiscale Energy Systems funded by the Korean government (MSIP) (NRF- 2012M3A6A7054855) (Y.-W.J. and M.C.), National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2020R1A2C3009115) (S.L. and J.H.N.), Deutsche Forschungsgemeinschaft (DFG) for funding in the framework of SPP 2196 (project PERFECT PVs, VA 991/3-1 and DE 830/22-1) (Y.V.), and DFG for funding in project Le747/64-1 (K.L.). Funding Information: Acknowledgments Funding: This study was funded by the Alexander von Humboldt Foundation via Humboldt Publisher Copyright: Copyright © 2021 The Authors, some rights reserved.

PY - 2021/12

Y1 - 2021/12

N2 - Efficient external radiation is essential for solar cells to achieve high power conversion efficiency (PCE). The classical limit of 1/2n2 (n, refractive index) for electroluminescence quantum efficiency (ELQE) has recently been approached by perovskite solar cells (PSCs). Photon recycling (PR) and light scattering can provide an opportunity to surpass this limit. We investigate the role of PR and scattering in practical device operation using a radiative PSC with an ELQE (13.7% at 1 sun) that significantly surpasses the classical limit (7.4%). We experimentally analyze the contributions of PR and scattering to this strong radiation. A novel optical model reveals an increase of 39 mV in the voltage of our PSC. This analysis can provide design principles for future PSCs to approach the Shockley-Queisser efficiency limit.

AB - Efficient external radiation is essential for solar cells to achieve high power conversion efficiency (PCE). The classical limit of 1/2n2 (n, refractive index) for electroluminescence quantum efficiency (ELQE) has recently been approached by perovskite solar cells (PSCs). Photon recycling (PR) and light scattering can provide an opportunity to surpass this limit. We investigate the role of PR and scattering in practical device operation using a radiative PSC with an ELQE (13.7% at 1 sun) that significantly surpasses the classical limit (7.4%). We experimentally analyze the contributions of PR and scattering to this strong radiation. A novel optical model reveals an increase of 39 mV in the voltage of our PSC. This analysis can provide design principles for future PSCs to approach the Shockley-Queisser efficiency limit.

UR - http://www.scopus.com/inward/record.url?scp=85122022931&partnerID=8YFLogxK

U2 - 10.1126/sciadv.abj1363

DO - 10.1126/sciadv.abj1363

M3 - Article

C2 - 34936442

AN - SCOPUS:85122022931

SN - 2375-2548

VL - 7

JO - Science Advances

JF - Science Advances

IS - 52

M1 - eabj1363

ER -

Effects of photon recycling and scattering in high-performance perovskite solar cells

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this