Efficient strategy for hollow carbon nanospheres embedded with nickel hydroxide nanocrystals and their excellent lithium-ion storage performances

Jeong Hoo Hong; Gi Dae Park; Su Hyun Yang; Jae Hun Choi; Yun Chan Kang

doi:10.1016/j.scriptamat.2020.07.032

Efficient strategy for hollow carbon nanospheres embedded with nickel hydroxide nanocrystals and their excellent lithium-ion storage performances

Jeong Hoo Hong, Gi Dae Park, Su Hyun Yang, Jae Hun Choi, Yun Chan Kang

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

In this study, an efficient supporting matrix for metal hydroxide, carbon hollow nanospheres are firstly applied for the synthesis of anode materials for lithium-ion batteries. Metal salt is infiltrated within the mesopores of carbon nanospheres, and then transforms into ultrafine metal hydroxide by in-situ precipitation. Immediate conversion reaction occurs between the ammonia solution and metal salt in liquid state to form ultrafine metal hydroxide. Hollow carbon nanospheres containing ultrafine Ni(OH)₂ nanocrystals within the shell exhibit high structural stability during repetitive conversion reactions with Li-ions, as well as superior cycling and rate performances when comparing to those of bare Ni(OH)₂ nanopowders.

Original language	English
Pages (from-to)	112-117
Number of pages	6
Journal	Scripta Materialia
Volume	188
DOIs	https://doi.org/10.1016/j.scriptamat.2020.07.032
Publication status	Published - 2020 Nov

Keywords

Nickel hydroxide
anode materials
hollow carbon nanospheres
in-situ precipitation
lithium-ion batteries

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.scriptamat.2020.07.032

Cite this

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title = "Efficient strategy for hollow carbon nanospheres embedded with nickel hydroxide nanocrystals and their excellent lithium-ion storage performances",

abstract = "In this study, an efficient supporting matrix for metal hydroxide, carbon hollow nanospheres are firstly applied for the synthesis of anode materials for lithium-ion batteries. Metal salt is infiltrated within the mesopores of carbon nanospheres, and then transforms into ultrafine metal hydroxide by in-situ precipitation. Immediate conversion reaction occurs between the ammonia solution and metal salt in liquid state to form ultrafine metal hydroxide. Hollow carbon nanospheres containing ultrafine Ni(OH)2 nanocrystals within the shell exhibit high structural stability during repetitive conversion reactions with Li-ions, as well as superior cycling and rate performances when comparing to those of bare Ni(OH)2 nanopowders.",

keywords = "Nickel hydroxide, anode materials, hollow carbon nanospheres, in-situ precipitation, lithium-ion batteries",

author = "Hong, {Jeong Hoo} and Park, {Gi Dae} and Yang, {Su Hyun} and Choi, {Jae Hun} and Kang, {Yun Chan}",

note = "Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( NRF-2019R1A2C2088047 ). Publisher Copyright: {\textcopyright} 2020",

year = "2020",

month = nov,

doi = "10.1016/j.scriptamat.2020.07.032",

language = "English",

volume = "188",

pages = "112--117",

journal = "Scripta Materialia",

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T1 - Efficient strategy for hollow carbon nanospheres embedded with nickel hydroxide nanocrystals and their excellent lithium-ion storage performances

AU - Hong, Jeong Hoo

AU - Park, Gi Dae

AU - Yang, Su Hyun

AU - Choi, Jae Hun

AU - Kang, Yun Chan

N1 - Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( NRF-2019R1A2C2088047 ). Publisher Copyright: © 2020

PY - 2020/11

Y1 - 2020/11

N2 - In this study, an efficient supporting matrix for metal hydroxide, carbon hollow nanospheres are firstly applied for the synthesis of anode materials for lithium-ion batteries. Metal salt is infiltrated within the mesopores of carbon nanospheres, and then transforms into ultrafine metal hydroxide by in-situ precipitation. Immediate conversion reaction occurs between the ammonia solution and metal salt in liquid state to form ultrafine metal hydroxide. Hollow carbon nanospheres containing ultrafine Ni(OH)2 nanocrystals within the shell exhibit high structural stability during repetitive conversion reactions with Li-ions, as well as superior cycling and rate performances when comparing to those of bare Ni(OH)2 nanopowders.

AB - In this study, an efficient supporting matrix for metal hydroxide, carbon hollow nanospheres are firstly applied for the synthesis of anode materials for lithium-ion batteries. Metal salt is infiltrated within the mesopores of carbon nanospheres, and then transforms into ultrafine metal hydroxide by in-situ precipitation. Immediate conversion reaction occurs between the ammonia solution and metal salt in liquid state to form ultrafine metal hydroxide. Hollow carbon nanospheres containing ultrafine Ni(OH)2 nanocrystals within the shell exhibit high structural stability during repetitive conversion reactions with Li-ions, as well as superior cycling and rate performances when comparing to those of bare Ni(OH)2 nanopowders.

KW - Nickel hydroxide

KW - anode materials

KW - hollow carbon nanospheres

KW - in-situ precipitation

KW - lithium-ion batteries

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U2 - 10.1016/j.scriptamat.2020.07.032

DO - 10.1016/j.scriptamat.2020.07.032

M3 - Article

AN - SCOPUS:85088223919

SN - 1359-6462

VL - 188

SP - 112

EP - 117

JO - Scripta Materialia

JF - Scripta Materialia

ER -

Efficient strategy for hollow carbon nanospheres embedded with nickel hydroxide nanocrystals and their excellent lithium-ion storage performances

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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