Electrochemical behavior of SiOx anodes with variation of oxygen ratio for Li-ion batteries

S. S. Suh; W. Y. Yoon; D. H. Kim; S. U. Kwon; J. H. Kim; Y. U. Kim; C. U. Jeong; Y. Y. Chan; S. H. Kang; J. K. Lee

doi:10.1016/j.electacta.2014.08.104

Electrochemical behavior of SiO_x anodes with variation of oxygen ratio for Li-ion batteries

S. S. Suh, W. Y. Yoon, D. H. Kim, S. U. Kwon, J. H. Kim, Y. U. Kim, C. U. Jeong, Y. Y. Chan, S. H. Kang, J. K. Lee

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The development of a method for synthesizing granulated silicon oxide nanoparticles (SiOxNPG) via athermal plasma and water granulation process and determination of the optimum stoichiometry of siliconoxide (SiOx) for achieving high electrochemical performance of an anode based on the developed materialare presented herein. The structure of the SiOxNPGs was confirmed by means of X-ray fluorescence,transmission electron microscopy, and X-ray diffraction. A high initial capacity of ~1196 mA•h•g-1wasachieved using the fabricated SiOxanode with x ~1.06, giving rise to a Coulombic efficiency of 75% afterthe first cycle. Further combination of SiOxwith graphite (3 wt%) for use as an anode gave rise to highcapacity (397 mA•h•g-1) and a very high Coulombic efficiency of 99.99% after 200 cycles. The physicalproperties of the synthesized materials were investigated based on micrometric analysis. On the basisof the volume expansion and cycle capacity, the optimal oxygen ratio of SiOxwas determined to bex ~1.06

Original language	English
Pages (from-to)	111-117
Number of pages	7
Journal	Electrochimica Acta
Volume	148
DOIs	https://doi.org/10.1016/j.electacta.2014.08.104
Publication status	Published - 2014 Dec 1

Bibliographical note

Funding Information:
This research was supported by a grant from the Fundamental R&D Program for Technology of World Premier Materials (WPM) funded by the Ministry of Knowledge Economy, Republic of Korea. The authors gratefully acknowledge the assistance from Daejoo Electronic Materials for supplying the SiO x raw material. This study was supported by a National Research Foundation (NRF) of Korea grant (2011-0028757) funded by the Ministry of Education, Science and Technology (MEST), the Korean Government.

Publisher Copyright:
© 2014 Elsevier Ltd. All rights reserved.

Keywords

Coulombic efficiency
Electrode expansion
Oxygen ratio
SiO

ASJC Scopus subject areas

General Chemical Engineering
Electrochemistry

Access to Document

10.1016/j.electacta.2014.08.104

Cite this

@article{ffb8cabc61894c5cb072170924d5b6d9,

title = "Electrochemical behavior of SiOx anodes with variation of oxygen ratio for Li-ion batteries",

abstract = "The development of a method for synthesizing granulated silicon oxide nanoparticles (SiOxNPG) via athermal plasma and water granulation process and determination of the optimum stoichiometry of siliconoxide (SiOx) for achieving high electrochemical performance of an anode based on the developed materialare presented herein. The structure of the SiOxNPGs was confirmed by means of X-ray fluorescence,transmission electron microscopy, and X-ray diffraction. A high initial capacity of ~1196 mA•h•g-1wasachieved using the fabricated SiOxanode with x ~1.06, giving rise to a Coulombic efficiency of 75% afterthe first cycle. Further combination of SiOxwith graphite (3 wt%) for use as an anode gave rise to highcapacity (397 mA•h•g-1) and a very high Coulombic efficiency of 99.99% after 200 cycles. The physicalproperties of the synthesized materials were investigated based on micrometric analysis. On the basisof the volume expansion and cycle capacity, the optimal oxygen ratio of SiOxwas determined to bex ~1.06",

keywords = "Coulombic efficiency, Electrode expansion, Oxygen ratio, SiO",

author = "Suh, {S. S.} and Yoon, {W. Y.} and Kim, {D. H.} and Kwon, {S. U.} and Kim, {J. H.} and Kim, {Y. U.} and Jeong, {C. U.} and Chan, {Y. Y.} and Kang, {S. H.} and Lee, {J. K.}",

note = "Funding Information: This research was supported by a grant from the Fundamental R&D Program for Technology of World Premier Materials (WPM) funded by the Ministry of Knowledge Economy, Republic of Korea. The authors gratefully acknowledge the assistance from Daejoo Electronic Materials for supplying the SiO x raw material. This study was supported by a National Research Foundation (NRF) of Korea grant (2011-0028757) funded by the Ministry of Education, Science and Technology (MEST), the Korean Government. Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",

year = "2014",

month = dec,

day = "1",

doi = "10.1016/j.electacta.2014.08.104",

language = "English",

volume = "148",

pages = "111--117",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Limited",

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TY - JOUR

T1 - Electrochemical behavior of SiOx anodes with variation of oxygen ratio for Li-ion batteries

AU - Suh, S. S.

AU - Yoon, W. Y.

AU - Kim, D. H.

AU - Kwon, S. U.

AU - Kim, J. H.

AU - Kim, Y. U.

AU - Jeong, C. U.

AU - Chan, Y. Y.

AU - Kang, S. H.

AU - Lee, J. K.

N1 - Funding Information: This research was supported by a grant from the Fundamental R&D Program for Technology of World Premier Materials (WPM) funded by the Ministry of Knowledge Economy, Republic of Korea. The authors gratefully acknowledge the assistance from Daejoo Electronic Materials for supplying the SiO x raw material. This study was supported by a National Research Foundation (NRF) of Korea grant (2011-0028757) funded by the Ministry of Education, Science and Technology (MEST), the Korean Government. Publisher Copyright: © 2014 Elsevier Ltd. All rights reserved.

PY - 2014/12/1

Y1 - 2014/12/1

N2 - The development of a method for synthesizing granulated silicon oxide nanoparticles (SiOxNPG) via athermal plasma and water granulation process and determination of the optimum stoichiometry of siliconoxide (SiOx) for achieving high electrochemical performance of an anode based on the developed materialare presented herein. The structure of the SiOxNPGs was confirmed by means of X-ray fluorescence,transmission electron microscopy, and X-ray diffraction. A high initial capacity of ~1196 mA•h•g-1wasachieved using the fabricated SiOxanode with x ~1.06, giving rise to a Coulombic efficiency of 75% afterthe first cycle. Further combination of SiOxwith graphite (3 wt%) for use as an anode gave rise to highcapacity (397 mA•h•g-1) and a very high Coulombic efficiency of 99.99% after 200 cycles. The physicalproperties of the synthesized materials were investigated based on micrometric analysis. On the basisof the volume expansion and cycle capacity, the optimal oxygen ratio of SiOxwas determined to bex ~1.06

AB - The development of a method for synthesizing granulated silicon oxide nanoparticles (SiOxNPG) via athermal plasma and water granulation process and determination of the optimum stoichiometry of siliconoxide (SiOx) for achieving high electrochemical performance of an anode based on the developed materialare presented herein. The structure of the SiOxNPGs was confirmed by means of X-ray fluorescence,transmission electron microscopy, and X-ray diffraction. A high initial capacity of ~1196 mA•h•g-1wasachieved using the fabricated SiOxanode with x ~1.06, giving rise to a Coulombic efficiency of 75% afterthe first cycle. Further combination of SiOxwith graphite (3 wt%) for use as an anode gave rise to highcapacity (397 mA•h•g-1) and a very high Coulombic efficiency of 99.99% after 200 cycles. The physicalproperties of the synthesized materials were investigated based on micrometric analysis. On the basisof the volume expansion and cycle capacity, the optimal oxygen ratio of SiOxwas determined to bex ~1.06

KW - Coulombic efficiency

KW - Electrode expansion

KW - Oxygen ratio

KW - SiO

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JO - Electrochimica Acta

JF - Electrochimica Acta

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