Electrochemical properties of iodine-containing lithium manganese oxide spinel

Chi Hwan Han; Young Sik Hong; Hyun Sil Hong; Keon Kim

doi:10.1016/S0378-7753(02)00098-8

Electrochemical properties of iodine-containing lithium manganese oxide spinel

Chi Hwan Han, Young Sik Hong, Hyun Sil Hong, Keon Kim

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Iodine-containing, cation-deficient, lithium manganese oxides (ICCD-LMO) are prepared by reaction of MnO₂ with LiI. The MnO₂ is completely transformed into spinel-structured compounds with a nominal composition of Li_1-δMn_2-2δO₄I_x. A sample prepared at 800 °C, viz. Li_0.99Mn_1.98O₄I_0.02, exhibits an initial discharge capacity of 113 mA h g^-1 with good cycleability and rate capability in the 4-V region. Iodine-containing, lithium-rich lithium manganese oxides (ICLR-LMO) are also prepared by reaction of LiMn₂O₄ with LiI, which results in a nominal composition of Li_1+xMn_2-xO₄I_x. Li_1.01Mn_1.99O₄I_0.02 shows a discharge capacity of 124 mA h g^-1 on the first cycle and 119 mA h g^-1 a on the 20th cycle. Both results indicate that a small amount of iodine species helps to maintain cycle performance.

Original language	English
Pages (from-to)	176-180
Number of pages	5
Journal	Journal of Power Sources
Volume	111
Issue number	1
DOIs	https://doi.org/10.1016/S0378-7753(02)00098-8
Publication status	Published - 2002 Sept 18

Bibliographical note

Funding Information:
We gratefully acknowledge financial support for this work by the Ministry of Education and Human Resources Development (BK-21) and the Korea Science and Engineering Foundation (KOSEF R01-2001-00045).

Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.

Keywords

Iodine-containing
Lithium manganese oxide
Lithium-ion battery

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/S0378-7753(02)00098-8

Cite this

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title = "Electrochemical properties of iodine-containing lithium manganese oxide spinel",

abstract = "Iodine-containing, cation-deficient, lithium manganese oxides (ICCD-LMO) are prepared by reaction of MnO2 with LiI. The MnO2 is completely transformed into spinel-structured compounds with a nominal composition of Li1-δMn2-2δO4Ix. A sample prepared at 800 °C, viz. Li0.99Mn1.98O4I0.02, exhibits an initial discharge capacity of 113 mA h g-1 with good cycleability and rate capability in the 4-V region. Iodine-containing, lithium-rich lithium manganese oxides (ICLR-LMO) are also prepared by reaction of LiMn2O4 with LiI, which results in a nominal composition of Li1+xMn2-xO4Ix. Li1.01Mn1.99O4I0.02 shows a discharge capacity of 124 mA h g-1 on the first cycle and 119 mA h g-1 a on the 20th cycle. Both results indicate that a small amount of iodine species helps to maintain cycle performance.",

keywords = "Iodine-containing, Lithium manganese oxide, Lithium-ion battery",

author = "Han, {Chi Hwan} and Hong, {Young Sik} and Hong, {Hyun Sil} and Keon Kim",

note = "Funding Information: We gratefully acknowledge financial support for this work by the Ministry of Education and Human Resources Development (BK-21) and the Korea Science and Engineering Foundation (KOSEF R01-2001-00045). Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2002",

month = sep,

day = "18",

doi = "10.1016/S0378-7753(02)00098-8",

language = "English",

volume = "111",

pages = "176--180",

journal = "Journal of Power Sources",

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TY - JOUR

T1 - Electrochemical properties of iodine-containing lithium manganese oxide spinel

AU - Han, Chi Hwan

AU - Hong, Young Sik

AU - Hong, Hyun Sil

AU - Kim, Keon

N1 - Funding Information: We gratefully acknowledge financial support for this work by the Ministry of Education and Human Resources Development (BK-21) and the Korea Science and Engineering Foundation (KOSEF R01-2001-00045). Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2002/9/18

Y1 - 2002/9/18

N2 - Iodine-containing, cation-deficient, lithium manganese oxides (ICCD-LMO) are prepared by reaction of MnO2 with LiI. The MnO2 is completely transformed into spinel-structured compounds with a nominal composition of Li1-δMn2-2δO4Ix. A sample prepared at 800 °C, viz. Li0.99Mn1.98O4I0.02, exhibits an initial discharge capacity of 113 mA h g-1 with good cycleability and rate capability in the 4-V region. Iodine-containing, lithium-rich lithium manganese oxides (ICLR-LMO) are also prepared by reaction of LiMn2O4 with LiI, which results in a nominal composition of Li1+xMn2-xO4Ix. Li1.01Mn1.99O4I0.02 shows a discharge capacity of 124 mA h g-1 on the first cycle and 119 mA h g-1 a on the 20th cycle. Both results indicate that a small amount of iodine species helps to maintain cycle performance.

AB - Iodine-containing, cation-deficient, lithium manganese oxides (ICCD-LMO) are prepared by reaction of MnO2 with LiI. The MnO2 is completely transformed into spinel-structured compounds with a nominal composition of Li1-δMn2-2δO4Ix. A sample prepared at 800 °C, viz. Li0.99Mn1.98O4I0.02, exhibits an initial discharge capacity of 113 mA h g-1 with good cycleability and rate capability in the 4-V region. Iodine-containing, lithium-rich lithium manganese oxides (ICLR-LMO) are also prepared by reaction of LiMn2O4 with LiI, which results in a nominal composition of Li1+xMn2-xO4Ix. Li1.01Mn1.99O4I0.02 shows a discharge capacity of 124 mA h g-1 on the first cycle and 119 mA h g-1 a on the 20th cycle. Both results indicate that a small amount of iodine species helps to maintain cycle performance.

KW - Iodine-containing

KW - Lithium manganese oxide

KW - Lithium-ion battery

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Electrochemical properties of iodine-containing lithium manganese oxide spinel

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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