Electron paramagnetic resonance and 1H nuclear magnetic resonance study of Y-doping effect on the hydrogen shallow donors in ZnO nanoparticles

Yeon Ho Lee; Kyu Won Lee; Gi Wan Jeon; Cheol Eui Lee

doi:10.1016/j.cap.2019.05.019

Electron paramagnetic resonance and ¹H nuclear magnetic resonance study of Y-doping effect on the hydrogen shallow donors in ZnO nanoparticles

Yeon Ho Lee, Kyu Won Lee, Gi Wan Jeon, Cheol Eui Lee

Department of Physics

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Hydrogen shallow donors in sol-gel-derived pristine and rare-earth Y-doped ZnO nanoparticles have been investigated by electron paramagnetic resonance (EPR) and high-resolution ¹H nuclear magnetic resonance (NMR). It is shown by EPR measurements that the energy level of the hydrogen shallow donors in the Y-doped ZnO is much deeper (E ∼ 174 meV) than in the pristine ZnO (E ∼ 75 meV). The temperature-dependent ¹H NMR chemical shift and linewidth measurements of the pristine and the Y-doped ZnO systems indicated that Y-doping effectively modifies the lattice environment and hinders the hydrogen motions in the ZnO nanoparticles.

Original language	English
Pages (from-to)	1015-1018
Number of pages	4
Journal	Current Applied Physics
Volume	19
Issue number	9
DOIs	https://doi.org/10.1016/j.cap.2019.05.019
Publication status	Published - 2019 Sept

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003 , 2016R1D1A1B03931144 and 2019R1A2C1002076 ). The Korea Basic Science Institute is acknowledged for the measurements.

Funding Information:
This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003, 2016R1D1A1B03931144 and 2019R1A2C1002076). The Korea Basic Science Institute is acknowledged for the measurements.

Publisher Copyright:
© 2019 Korean Physical Society

Keywords

Electron paramagnetic resonance
Y-doping effect
ZnO

ASJC Scopus subject areas

Materials Science(all)
Physics and Astronomy(all)

Access to Document

10.1016/j.cap.2019.05.019

Cite this

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title = "Electron paramagnetic resonance and 1H nuclear magnetic resonance study of Y-doping effect on the hydrogen shallow donors in ZnO nanoparticles",

abstract = "Hydrogen shallow donors in sol-gel-derived pristine and rare-earth Y-doped ZnO nanoparticles have been investigated by electron paramagnetic resonance (EPR) and high-resolution 1H nuclear magnetic resonance (NMR). It is shown by EPR measurements that the energy level of the hydrogen shallow donors in the Y-doped ZnO is much deeper (E ∼ 174 meV) than in the pristine ZnO (E ∼ 75 meV). The temperature-dependent 1H NMR chemical shift and linewidth measurements of the pristine and the Y-doped ZnO systems indicated that Y-doping effectively modifies the lattice environment and hinders the hydrogen motions in the ZnO nanoparticles.",

keywords = "Electron paramagnetic resonance, Y-doping effect, ZnO",

author = "Lee, {Yeon Ho} and Lee, {Kyu Won} and Jeon, {Gi Wan} and Lee, {Cheol Eui}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003 , 2016R1D1A1B03931144 and 2019R1A2C1002076 ). The Korea Basic Science Institute is acknowledged for the measurements. Funding Information: This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003, 2016R1D1A1B03931144 and 2019R1A2C1002076). The Korea Basic Science Institute is acknowledged for the measurements. Publisher Copyright: {\textcopyright} 2019 Korean Physical Society",

year = "2019",

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doi = "10.1016/j.cap.2019.05.019",

language = "English",

volume = "19",

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AU - Lee, Yeon Ho

AU - Lee, Kyu Won

AU - Jeon, Gi Wan

AU - Lee, Cheol Eui

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003 , 2016R1D1A1B03931144 and 2019R1A2C1002076 ). The Korea Basic Science Institute is acknowledged for the measurements. Funding Information: This work was supported by the National Research Foundation of Korea (Project Nos. 2016R1D1A1A09917003, 2016R1D1A1B03931144 and 2019R1A2C1002076). The Korea Basic Science Institute is acknowledged for the measurements. Publisher Copyright: © 2019 Korean Physical Society

PY - 2019/9

Y1 - 2019/9

N2 - Hydrogen shallow donors in sol-gel-derived pristine and rare-earth Y-doped ZnO nanoparticles have been investigated by electron paramagnetic resonance (EPR) and high-resolution 1H nuclear magnetic resonance (NMR). It is shown by EPR measurements that the energy level of the hydrogen shallow donors in the Y-doped ZnO is much deeper (E ∼ 174 meV) than in the pristine ZnO (E ∼ 75 meV). The temperature-dependent 1H NMR chemical shift and linewidth measurements of the pristine and the Y-doped ZnO systems indicated that Y-doping effectively modifies the lattice environment and hinders the hydrogen motions in the ZnO nanoparticles.

AB - Hydrogen shallow donors in sol-gel-derived pristine and rare-earth Y-doped ZnO nanoparticles have been investigated by electron paramagnetic resonance (EPR) and high-resolution 1H nuclear magnetic resonance (NMR). It is shown by EPR measurements that the energy level of the hydrogen shallow donors in the Y-doped ZnO is much deeper (E ∼ 174 meV) than in the pristine ZnO (E ∼ 75 meV). The temperature-dependent 1H NMR chemical shift and linewidth measurements of the pristine and the Y-doped ZnO systems indicated that Y-doping effectively modifies the lattice environment and hinders the hydrogen motions in the ZnO nanoparticles.

KW - Electron paramagnetic resonance

KW - Y-doping effect

KW - ZnO

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