Enantioselective syntheses of decursinol angelate and decursin

Jongdoo Lim; Ik Hwan Kim; Hyeon Ho Kim; Kyung Seop Ahn; Hogyu Han

doi:10.1016/S0040-4039(01)00642-6

Enantioselective syntheses of decursinol angelate and decursin

Jongdoo Lim, Ik Hwan Kim, Hyeon Ho Kim, Kyung Seop Ahn, Hogyu Han^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.

Original language	English
Pages (from-to)	4001-4003
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4039(01)00642-6
Publication status	Published - 2001 Jun 11

Bibliographical note

Funding Information:
This work was supported by the Highly Advanced Program (G7) from the Ministry of Science and Technology, Korea (Grant No. 00-G-NB-01-C-008). Fellowship support from the BK21 Program (J.L.) is gratefully acknowledged. The authors would like to thank Professor Nakcheol Jeong for his insightful comments about this work.

Copyright:
Copyright 2007 Elsevier B.V., All rights reserved.

Keywords

Catalytic asymmetric epoxidation
Decursin
Decursinol
Decursinol angelate
Protein kinase C

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)00642-6

Cite this

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title = "Enantioselective syntheses of decursinol angelate and decursin",

abstract = "The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.",

keywords = "Catalytic asymmetric epoxidation, Decursin, Decursinol, Decursinol angelate, Protein kinase C",

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note = "Funding Information: This work was supported by the Highly Advanced Program (G7) from the Ministry of Science and Technology, Korea (Grant No. 00-G-NB-01-C-008). Fellowship support from the BK21 Program (J.L.) is gratefully acknowledged. The authors would like to thank Professor Nakcheol Jeong for his insightful comments about this work. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.",

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doi = "10.1016/S0040-4039(01)00642-6",

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AU - Lim, Jongdoo

AU - Kim, Ik Hwan

AU - Kim, Hyeon Ho

AU - Ahn, Kyung Seop

AU - Han, Hogyu

N1 - Funding Information: This work was supported by the Highly Advanced Program (G7) from the Ministry of Science and Technology, Korea (Grant No. 00-G-NB-01-C-008). Fellowship support from the BK21 Program (J.L.) is gratefully acknowledged. The authors would like to thank Professor Nakcheol Jeong for his insightful comments about this work. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.

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N2 - The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.

AB - The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.

KW - Catalytic asymmetric epoxidation

KW - Decursin

KW - Decursinol

KW - Decursinol angelate

KW - Protein kinase C

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Enantioselective syntheses of decursinol angelate and decursin

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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