Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives

Jeong Wook Oh; Yeon Ok Lee; Tae Hyun Kim; Kyoung Chul Ko; Jin Yong Lee; Hasuck Kim; Jong Seung Kim

doi:10.1002/anie.200804669

Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives

Jeong Wook Oh^*
, Yeon Ok Lee
, Tae Hyun Kim
, Kyoung Chul Ko
, Jin Yong Lee
, Hasuck Kim
, Jong Seung Kim

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.

Original language	English
Pages (from-to)	2522-2524
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	14
DOIs	https://doi.org/10.1002/anie.200804669
Publication status	Published - 2009 Mar 23

Keywords

Alkynes
Chemiluminescence
Donor-acceptor systems
Electrochemistry
Radical ions

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200804669

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title = "Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives",

abstract = "A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.",

keywords = "Alkynes, Chemiluminescence, Donor-acceptor systems, Electrochemistry, Radical ions",

author = "Oh, \{Jeong Wook\} and Lee, \{Yeon Ok\} and Kim, \{Tae Hyun\} and Ko, \{Kyoung Chul\} and Lee, \{Jin Yong\} and Hasuck Kim and Kim, \{Jong Seung\}",

year = "2009",

month = mar,

day = "23",

doi = "10.1002/anie.200804669",

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T1 - Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives

AU - Oh, Jeong Wook

AU - Lee, Yeon Ok

AU - Kim, Tae Hyun

AU - Ko, Kyoung Chul

AU - Lee, Jin Yong

AU - Kim, Hasuck

AU - Kim, Jong Seung

PY - 2009/3/23

Y1 - 2009/3/23

N2 - A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.

AB - A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.

KW - Alkynes

KW - Chemiluminescence

KW - Donor-acceptor systems

KW - Electrochemistry

KW - Radical ions

UR - https://www.scopus.com/pages/publications/70349770357

U2 - 10.1002/anie.200804669

DO - 10.1002/anie.200804669

M3 - Article

C2 - 19040242

AN - SCOPUS:70349770357

SN - 1433-7851

VL - 48

SP - 2522

EP - 2524

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives

Abstract

Keywords

ASJC Scopus subject areas

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