## Abstract

We derive an equality for non-equilibrium statistical mechanics in finite-dimensional quantum systems. The equality concerns the worst-case work output of a time-dependent Hamiltonian protocol in the presence of a Markovian heat bath. It has the form 'worst-case work = penalty - optimum'. The equality holds for all rates of changing the Hamiltonian and can be used to derive the optimum by setting the penalty to 0. The optimum term contains the max entropy of the initial state, rather than the von Neumann entropy, thus recovering recent results from single-shot statistical mechanics. Energy coherences can arise during the protocol but are assumed not to be present initially. We apply the equality to an electron box.

Original language | English |
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Article number | 043013 |

Journal | New Journal of Physics |

Volume | 19 |

Issue number | 4 |

DOIs | |

Publication status | Published - 2017 Apr |

### Bibliographical note

Publisher Copyright:© 2017 IOP Publishing Ltd and Deutsche Physikalische Gesellschaft.

## Keywords

- Crooks fluctuation theorem
- electron box
- entropy
- single shot statistical mechanics

## ASJC Scopus subject areas

- General Physics and Astronomy