Exploring the potential of MIL-derived nanocomposites to enhance performance of lithium-ion batteries

Bhavana Joshi; Edmund Samuel; Yong Il Kim; Hae Seok Lee; Mark T. Swihart; Sam S. Yoon

doi:10.1016/j.cej.2023.141961

Exploring the potential of MIL-derived nanocomposites to enhance performance of lithium-ion batteries

Bhavana Joshi, Edmund Samuel, Yong Il Kim, Hae Seok Lee, Mark T. Swihart, Sam S. Yoon

Research output: Contribution to journal › Review article › peer-review

3 Citations (Scopus)

Abstract

Developing high-performance energy storage and conversion devices is critical for implementing renewable and sustainable energy technologies. Nanoporous Matériaux de l′Institut Lavoisier (MIL)-type metal–organic framework materials can accommodate porous carbonaceous substances, metal oxides, or chalcogenides or can be fashioned into porous composites. Several of these structures show great potential for use in energy storage devices. Most MILs include high-valent cations, such as iron, vanadium, and chromium, and can accommodate abundant redox-active species in their scaffolds. Substantial recent research on MIL-based lithium-ion-battery (LIB) electrodes has highlighted the synergistic impact of restructuring the MIL morphology on enhancing specific lithium uptake capacities. Several studies have also explored the rate capabilities of MIL-based electrodes with different energy storage mechanisms. In this review, advanced MIL-based composites for LIBs compatible with electric vehicles are comprehensively analyzed, focusing on achieving rapid charging and long-term cycling performance under high-current-loading conditions. The challenges, future prospects, and research directions for design and synthesis of MIL-based composites are also discussed.

Original language	English
Article number	141961
Journal	Chemical Engineering Journal
Volume	461
DOIs	https://doi.org/10.1016/j.cej.2023.141961
Publication status	Published - 2023 Apr 1

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2020R1A5A1018153).

Publisher Copyright:
© 2023 Elsevier B.V.

Keywords

Lithium-ion battery
Materials from the Lavoisier Institute (MIL)
Metal–ligand matrix
Self-assembling coordination chemistry

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Industrial and Manufacturing Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.cej.2023.141961

Cite this

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title = "Exploring the potential of MIL-derived nanocomposites to enhance performance of lithium-ion batteries",

abstract = "Developing high-performance energy storage and conversion devices is critical for implementing renewable and sustainable energy technologies. Nanoporous Mat{\'e}riaux de l′Institut Lavoisier (MIL)-type metal–organic framework materials can accommodate porous carbonaceous substances, metal oxides, or chalcogenides or can be fashioned into porous composites. Several of these structures show great potential for use in energy storage devices. Most MILs include high-valent cations, such as iron, vanadium, and chromium, and can accommodate abundant redox-active species in their scaffolds. Substantial recent research on MIL-based lithium-ion-battery (LIB) electrodes has highlighted the synergistic impact of restructuring the MIL morphology on enhancing specific lithium uptake capacities. Several studies have also explored the rate capabilities of MIL-based electrodes with different energy storage mechanisms. In this review, advanced MIL-based composites for LIBs compatible with electric vehicles are comprehensively analyzed, focusing on achieving rapid charging and long-term cycling performance under high-current-loading conditions. The challenges, future prospects, and research directions for design and synthesis of MIL-based composites are also discussed.",

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author = "Bhavana Joshi and Edmund Samuel and Kim, {Yong Il} and Lee, {Hae Seok} and Swihart, {Mark T.} and Yoon, {Sam S.}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2020R1A5A1018153). Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

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AU - Samuel, Edmund

AU - Kim, Yong Il

AU - Lee, Hae Seok

AU - Swihart, Mark T.

AU - Yoon, Sam S.

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2020R1A5A1018153). Publisher Copyright: © 2023 Elsevier B.V.

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AB - Developing high-performance energy storage and conversion devices is critical for implementing renewable and sustainable energy technologies. Nanoporous Matériaux de l′Institut Lavoisier (MIL)-type metal–organic framework materials can accommodate porous carbonaceous substances, metal oxides, or chalcogenides or can be fashioned into porous composites. Several of these structures show great potential for use in energy storage devices. Most MILs include high-valent cations, such as iron, vanadium, and chromium, and can accommodate abundant redox-active species in their scaffolds. Substantial recent research on MIL-based lithium-ion-battery (LIB) electrodes has highlighted the synergistic impact of restructuring the MIL morphology on enhancing specific lithium uptake capacities. Several studies have also explored the rate capabilities of MIL-based electrodes with different energy storage mechanisms. In this review, advanced MIL-based composites for LIBs compatible with electric vehicles are comprehensively analyzed, focusing on achieving rapid charging and long-term cycling performance under high-current-loading conditions. The challenges, future prospects, and research directions for design and synthesis of MIL-based composites are also discussed.

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KW - Metal–ligand matrix

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Exploring the potential of MIL-derived nanocomposites to enhance performance of lithium-ion batteries

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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