Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation

Shin Kun Ryi; Jong Soo Park; Sung Hoon Choi; Sung Ho Cho; Sung Hyun Kim

doi:10.1016/j.seppur.2005.06.017

Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation

Shin Kun Ryi, Jong Soo Park, Sung Hoon Choi, Sung Ho Cho, Sung Hyun Kim

* Honorary professors

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Nickel porous membrane was successfully made for hydrogen separation or metal support for Pd and/or Pd-alloy dense membrane. Ni porous membrane made by uniaxial pressing has so small and uniform pore size to be the support of dense membrane. We fabricated the Ni porous membrane with two kinds of Ni powder (average particle size of 0.15 and 5 μm). It was clarified that the broad distribution of particle size is very important to the packing degree of membrane and selectivity of H₂ and H₂ permeation was contributed by Knudsen and surface diffusion from the results of permeation test under room temperature to 200 °C. With various particle size as well as the increasing compressed pressure, we could obtain more compactness, thereby achieving the satisfactory selectivity of H₂.

Original language	English
Pages (from-to)	148-155
Number of pages	8
Journal	Separation and Purification Technology
Volume	47
Issue number	3
DOIs	https://doi.org/10.1016/j.seppur.2005.06.017
Publication status	Published - 2006 Jan

Keywords

Hydrogen
Nickel powder
Porous nickel membrane
Separation
Uniaxial pressing

ASJC Scopus subject areas

Analytical Chemistry
Filtration and Separation

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10.1016/j.seppur.2005.06.017

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title = "Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation",

abstract = "Nickel porous membrane was successfully made for hydrogen separation or metal support for Pd and/or Pd-alloy dense membrane. Ni porous membrane made by uniaxial pressing has so small and uniform pore size to be the support of dense membrane. We fabricated the Ni porous membrane with two kinds of Ni powder (average particle size of 0.15 and 5 μm). It was clarified that the broad distribution of particle size is very important to the packing degree of membrane and selectivity of H2 and H2 permeation was contributed by Knudsen and surface diffusion from the results of permeation test under room temperature to 200 °C. With various particle size as well as the increasing compressed pressure, we could obtain more compactness, thereby achieving the satisfactory selectivity of H2.",

keywords = "Hydrogen, Nickel powder, Porous nickel membrane, Separation, Uniaxial pressing",

author = "Ryi, {Shin Kun} and Park, {Jong Soo} and Choi, {Sung Hoon} and Cho, {Sung Ho} and Kim, {Sung Hyun}",

note = "Funding Information: The research was performed for the Carbon Dioxide Reduction & Sequestration. R&D Center, one of the 21st century Frontier R&D Programs funded by the Ministry of Science & Technology of Korea. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2006",

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doi = "10.1016/j.seppur.2005.06.017",

language = "English",

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journal = "Separation and Purification Technology",

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T1 - Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation

AU - Ryi, Shin Kun

AU - Park, Jong Soo

AU - Choi, Sung Hoon

AU - Cho, Sung Ho

AU - Kim, Sung Hyun

N1 - Funding Information: The research was performed for the Carbon Dioxide Reduction & Sequestration. R&D Center, one of the 21st century Frontier R&D Programs funded by the Ministry of Science & Technology of Korea. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2006/1

Y1 - 2006/1

N2 - Nickel porous membrane was successfully made for hydrogen separation or metal support for Pd and/or Pd-alloy dense membrane. Ni porous membrane made by uniaxial pressing has so small and uniform pore size to be the support of dense membrane. We fabricated the Ni porous membrane with two kinds of Ni powder (average particle size of 0.15 and 5 μm). It was clarified that the broad distribution of particle size is very important to the packing degree of membrane and selectivity of H2 and H2 permeation was contributed by Knudsen and surface diffusion from the results of permeation test under room temperature to 200 °C. With various particle size as well as the increasing compressed pressure, we could obtain more compactness, thereby achieving the satisfactory selectivity of H2.

AB - Nickel porous membrane was successfully made for hydrogen separation or metal support for Pd and/or Pd-alloy dense membrane. Ni porous membrane made by uniaxial pressing has so small and uniform pore size to be the support of dense membrane. We fabricated the Ni porous membrane with two kinds of Ni powder (average particle size of 0.15 and 5 μm). It was clarified that the broad distribution of particle size is very important to the packing degree of membrane and selectivity of H2 and H2 permeation was contributed by Knudsen and surface diffusion from the results of permeation test under room temperature to 200 °C. With various particle size as well as the increasing compressed pressure, we could obtain more compactness, thereby achieving the satisfactory selectivity of H2.

KW - Hydrogen

KW - Nickel powder

KW - Porous nickel membrane

KW - Separation

KW - Uniaxial pressing

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JO - Separation and Purification Technology

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Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation

Abstract

Keywords

ASJC Scopus subject areas

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