Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

Taegon Kang; Roey J. Amir; Anzar Khan; Kaoru Ohshimizu; Jasmine N. Hunt; Kulandaivelu Sivanandan; Maria I. Montañez; Michael Malkoch; Mitsuru Ueda; Craig J. Hawker

doi:10.1039/b921598k

Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

Taegon Kang
, Roey J. Amir
, Anzar Khan
, Kaoru Ohshimizu
, Jasmine N. Hunt
, Kulandaivelu Sivanandan
, Maria I. Montañez
, Michael Malkoch
, Mitsuru Ueda
, Craig J. Hawker

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions - 'epoxy-amine' and 'thiol-ene' coupling - for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.

Original language	English
Pages (from-to)	1556-1558
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	9
DOIs	https://doi.org/10.1039/b921598k
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b921598k

Cite this

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abstract = "A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions - 'epoxy-amine' and 'thiol-ene' coupling - for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.",

author = "Taegon Kang and Amir, \{Roey J.\} and Anzar Khan and Kaoru Ohshimizu and Hunt, \{Jasmine N.\} and Kulandaivelu Sivanandan and Monta{\~n}ez, \{Maria I.\} and Michael Malkoch and Mitsuru Ueda and Hawker, \{Craig J.\}",

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language = "English",

volume = "46",

pages = "1556--1558",

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T1 - Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

AU - Kang, Taegon

AU - Amir, Roey J.

AU - Khan, Anzar

AU - Ohshimizu, Kaoru

AU - Hunt, Jasmine N.

AU - Sivanandan, Kulandaivelu

AU - Montañez, Maria I.

AU - Malkoch, Michael

AU - Ueda, Mitsuru

AU - Hawker, Craig J.

PY - 2010

Y1 - 2010

N2 - A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions - 'epoxy-amine' and 'thiol-ene' coupling - for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.

AB - A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions - 'epoxy-amine' and 'thiol-ene' coupling - for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.

UR - https://www.scopus.com/pages/publications/76949103844

U2 - 10.1039/b921598k

DO - 10.1039/b921598k

M3 - Article

C2 - 20162180

AN - SCOPUS:76949103844

SN - 1359-7345

VL - 46

SP - 1556

EP - 1558

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

Abstract

ASJC Scopus subject areas

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