Facile aqueous-phase synthesis of copper sulfide nanofibers

Zengmin Tang; Sang Hyuk Im; Woo Sik Kim; Taekyung Yu

doi:10.1016/j.jcrysgro.2016.07.046

Facile aqueous-phase synthesis of copper sulfide nanofibers

Zengmin Tang, Sang Hyuk Im, Woo Sik Kim, Taekyung Yu

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

We report a facile aqueous-phase synthetic route to vine-like copper sulfide (CuS) nanofibers prepared by reacting elemental sulfur with Cu⁺-branched polyethyleneimine (BPEI) complex obtained by the reaction of Cu²⁺ with ascorbic acid in the presence of BPEI. By controlling the concentration of BPEI, we could easily control the morphology of CuS from nanofibers to hollow nanoparticles. We also found that concentration of BPEI and the presence of halide anion would play important roles in the formation of vine-like CuS nanofibers.

Original language	English
Pages (from-to)	172-175
Number of pages	4
Journal	Journal of Crystal Growth
Volume	469
DOIs	https://doi.org/10.1016/j.jcrysgro.2016.07.046
Publication status	Published - 2017 Jul 1
Externally published	Yes

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2014R1A5A1009799) and by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2015R1C1A1A01054109 and NRF-2016M3D1A1021140). This work was also supported by a grant from Kyung Hee University in 2014 (KHU-20140324).

Publisher Copyright:
© 2016 Elsevier B.V.

Keywords

A1. Growth model
A1. Nanostructures
A2. Crystal growth from solution
B1. Nanomaterials
B1. Sulfides
B2. Semiconducting II–VI materials

ASJC Scopus subject areas

Condensed Matter Physics
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jcrysgro.2016.07.046

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title = "Facile aqueous-phase synthesis of copper sulfide nanofibers",

abstract = "We report a facile aqueous-phase synthetic route to vine-like copper sulfide (CuS) nanofibers prepared by reacting elemental sulfur with Cu+-branched polyethyleneimine (BPEI) complex obtained by the reaction of Cu2+ with ascorbic acid in the presence of BPEI. By controlling the concentration of BPEI, we could easily control the morphology of CuS from nanofibers to hollow nanoparticles. We also found that concentration of BPEI and the presence of halide anion would play important roles in the formation of vine-like CuS nanofibers.",

keywords = "A1. Growth model, A1. Nanostructures, A2. Crystal growth from solution, B1. Nanomaterials, B1. Sulfides, B2. Semiconducting II–VI materials",

author = "Zengmin Tang and Im, {Sang Hyuk} and Kim, {Woo Sik} and Taekyung Yu",

note = "Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2014R1A5A1009799) and by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2015R1C1A1A01054109 and NRF-2016M3D1A1021140). This work was also supported by a grant from Kyung Hee University in 2014 (KHU-20140324). Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

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doi = "10.1016/j.jcrysgro.2016.07.046",

language = "English",

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AU - Tang, Zengmin

AU - Im, Sang Hyuk

AU - Kim, Woo Sik

AU - Yu, Taekyung

N1 - Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2014R1A5A1009799) and by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2015R1C1A1A01054109 and NRF-2016M3D1A1021140). This work was also supported by a grant from Kyung Hee University in 2014 (KHU-20140324). Publisher Copyright: © 2016 Elsevier B.V.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - We report a facile aqueous-phase synthetic route to vine-like copper sulfide (CuS) nanofibers prepared by reacting elemental sulfur with Cu+-branched polyethyleneimine (BPEI) complex obtained by the reaction of Cu2+ with ascorbic acid in the presence of BPEI. By controlling the concentration of BPEI, we could easily control the morphology of CuS from nanofibers to hollow nanoparticles. We also found that concentration of BPEI and the presence of halide anion would play important roles in the formation of vine-like CuS nanofibers.

AB - We report a facile aqueous-phase synthetic route to vine-like copper sulfide (CuS) nanofibers prepared by reacting elemental sulfur with Cu+-branched polyethyleneimine (BPEI) complex obtained by the reaction of Cu2+ with ascorbic acid in the presence of BPEI. By controlling the concentration of BPEI, we could easily control the morphology of CuS from nanofibers to hollow nanoparticles. We also found that concentration of BPEI and the presence of halide anion would play important roles in the formation of vine-like CuS nanofibers.

KW - A1. Growth model

KW - A1. Nanostructures

KW - A2. Crystal growth from solution

KW - B1. Nanomaterials

KW - B1. Sulfides

KW - B2. Semiconducting II–VI materials

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DO - 10.1016/j.jcrysgro.2016.07.046

M3 - Article

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SN - 0022-0248

VL - 469

SP - 172

EP - 175

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

ER -

Facile aqueous-phase synthesis of copper sulfide nanofibers

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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