Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions

Qian Yong Cao; Tuhin Pradhan; Sungtae Kim; Jong Seung Kim

doi:10.1021/ol201722d

Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions

Qian Yong Cao, Tuhin Pradhan, Sungtae Kim, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H•••O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and ¹H NMR titration results.

Original language	English
Pages (from-to)	4386-4389
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	16
DOIs	https://doi.org/10.1021/ol201722d
Publication status	Published - 2011 Aug 19

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol201722d

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abstract = "A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H•••O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and 1H NMR titration results.",

author = "Cao, {Qian Yong} and Tuhin Pradhan and Sungtae Kim and Kim, {Jong Seung}",

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Y1 - 2011/8/19

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AB - A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H•••O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and 1H NMR titration results.

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Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions

Abstract

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