Ferrocene-based novel electrochemical chemodosimeter for mercury ion recognition

Qian Yong Cao; Min Hee Lee; Jun Feng Zhang; Wen Xiu Ren; Jong Seung Kim

doi:10.1016/j.tetlet.2011.03.121

Ferrocene-based novel electrochemical chemodosimeter for mercury ion recognition

Qian Yong Cao, Min Hee Lee, Jun Feng Zhang, Wen Xiu Ren, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A new ferrocene-based electrochemical chemodosimeter (1) for mercury(II) ion was prepared and characterized by X-ray crystal analysis. Among various metal ions, 1 displays highly selective electrochemical signaling changes for Hg²⁺ over other metal ions in regard to a mercury-promoted intramolecular cyclic guanylation of thiourea.

Original language	English
Pages (from-to)	2786-2789
Number of pages	4
Journal	Tetrahedron Letters
Volume	52
Issue number	21
DOIs	https://doi.org/10.1016/j.tetlet.2011.03.121
Publication status	Published - 2011 May 25

Bibliographical note

Funding Information:
This work was supported by the CRI project ( 2010-0000728 ) (J.S.K.). Q.-Y. C. acknowledges the funds from the Bureau of Education of Jiangxi Province ( GJJ09074 ) and the program for innovative research team of Nanchang University.

Keywords

Chemodosimeter
Electrochemistry
Ferrocene
Mercury

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2011.03.121

Cite this

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title = "Ferrocene-based novel electrochemical chemodosimeter for mercury ion recognition",

abstract = "A new ferrocene-based electrochemical chemodosimeter (1) for mercury(II) ion was prepared and characterized by X-ray crystal analysis. Among various metal ions, 1 displays highly selective electrochemical signaling changes for Hg2+ over other metal ions in regard to a mercury-promoted intramolecular cyclic guanylation of thiourea.",

keywords = "Chemodosimeter, Electrochemistry, Ferrocene, Mercury",

author = "Cao, {Qian Yong} and Lee, {Min Hee} and Zhang, {Jun Feng} and Ren, {Wen Xiu} and Kim, {Jong Seung}",

note = "Funding Information: This work was supported by the CRI project ( 2010-0000728 ) (J.S.K.). Q.-Y. C. acknowledges the funds from the Bureau of Education of Jiangxi Province ( GJJ09074 ) and the program for innovative research team of Nanchang University. ",

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AU - Cao, Qian Yong

AU - Lee, Min Hee

AU - Zhang, Jun Feng

AU - Ren, Wen Xiu

AU - Kim, Jong Seung

N1 - Funding Information: This work was supported by the CRI project ( 2010-0000728 ) (J.S.K.). Q.-Y. C. acknowledges the funds from the Bureau of Education of Jiangxi Province ( GJJ09074 ) and the program for innovative research team of Nanchang University.

PY - 2011/5/25

Y1 - 2011/5/25

N2 - A new ferrocene-based electrochemical chemodosimeter (1) for mercury(II) ion was prepared and characterized by X-ray crystal analysis. Among various metal ions, 1 displays highly selective electrochemical signaling changes for Hg2+ over other metal ions in regard to a mercury-promoted intramolecular cyclic guanylation of thiourea.

AB - A new ferrocene-based electrochemical chemodosimeter (1) for mercury(II) ion was prepared and characterized by X-ray crystal analysis. Among various metal ions, 1 displays highly selective electrochemical signaling changes for Hg2+ over other metal ions in regard to a mercury-promoted intramolecular cyclic guanylation of thiourea.

KW - Chemodosimeter

KW - Electrochemistry

KW - Ferrocene

KW - Mercury

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JF - Tetrahedron Letters

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Ferrocene-based novel electrochemical chemodosimeter for mercury ion recognition

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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