Fibril-Type Textile Electrodes Enabling Extremely High Areal Capacity through Pseudocapacitive Electroplating onto Chalcogenide Nanoparticle-Encapsulated Fibrils

Woojae Chang, Donghyeon Nam, Seokmin Lee, Younji Ko, Cheong Hoon Kwon, Yongmin Ko, Jinhan Cho

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Effective incorporation of conductive and energy storage materials into 3D porous textiles plays a pivotal role in developing and designing high-performance energy storage devices. Here, a fibril-type textile pseudocapacitor electrode with outstanding capacity, good rate capability, and excellent mechanical stability through controlled interfacial interaction-induced electroplating is reported. First, tetraoctylammonium bromide-stabilized copper sulfide nanoparticles (TOABr-CuS NPs) are uniformly assembled onto cotton textiles. This approach converts insulating textiles to conductive textiles preserving their intrinsically porous structure with an extremely large surface area. For the preparation of textile current collector with bulk metal-like electrical conductivity, Ni is additionally electroplated onto the CuS NP-assembled textiles (i.e., Ni-EPT). Furthermore, a pseudocapacitive NiCo-layered double hydroxide (LDH) layer is subsequently electroplated onto Ni-EPT for the cathode. The formed NiCo-LDH electroplated textiles (i.e., NiCo-EPT) exhibit a high areal capacitance of 12.2 F cm−2 (at 10 mA cm−2), good rate performance, and excellent cycling stability. Particularly, the areal capacity of NiCo-EPT can be further increased through their subsequent stacking. The 3-stack NiCo-EPT delivers an unprecedentedly high areal capacitance of 28.8 F cm−2 (at 30 mA cm−2), which outperforms those of textile-based pseudocapacitor electrodes reported to date.

Original languageEnglish
Article number2203800
JournalAdvanced Science
Volume9
Issue number33
DOIs
Publication statusPublished - 2022 Nov 24

Bibliographical note

Funding Information:
This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Ministry of Science, ICT & Future Planning (MSIP) (2021R1A2C3004151 and 2021R1F1A1059898).

Publisher Copyright:
© 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.

Keywords

  • chalcogenide nanoparticles
  • energy storage
  • multi-stacking
  • pseudocapacitve electroplating
  • textile pseudocapacitor

ASJC Scopus subject areas

  • Medicine (miscellaneous)
  • General Chemical Engineering
  • General Materials Science
  • Biochemistry, Genetics and Molecular Biology (miscellaneous)
  • General Engineering
  • General Physics and Astronomy

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