Fine-tuning of wettability in a single metal-organic framework: Via postcoordination modification and its reduced graphene oxide aerogel for oil-water separation

Sunhwi Eom; Dong Won Kang; Minjung Kang; Jong Hyeak Choe; Hyojin Kim; Dae Won Kim; Chang Seop Hong

doi:10.1039/c8sc04581j

Fine-tuning of wettability in a single metal-organic framework: Via postcoordination modification and its reduced graphene oxide aerogel for oil-water separation

Sunhwi Eom, Dong Won Kang, Minjung Kang, Jong Hyeak Choe, Hyojin Kim, Dae Won Kim, Chang Seop Hong

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Elaborate control of wettability in a single platform is essential for materials' applications towards oil-water separation, but it still remains challenging. Herein, we performed postcoordination modification of Mg₂(dobpdc) with monoamines of various alkyl chain lengths, enabling both long-term hydrolytic stability and facile fine-tuning of wettability. An efficient separation of oil-water mixtures was achieved by using the octylamine-appended framework (OctA). We also prepared an OctA/reduced graphene oxide aerogel that showed exceptional absorption capacities towards organic solvents and oil as well as superb recyclability with maintained absorbency.

Original language	English
Pages (from-to)	2663-2669
Number of pages	7
Journal	Chemical Science
Volume	10
Issue number	9
DOIs	https://doi.org/10.1039/c8sc04581j
Publication status	Published - 2019

Bibliographical note

Funding Information:
This work was supported by a Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT, & Future Planning (MSIP)) (NRF-2012-0008901) and by the Basic Science Research Program (NRF-2018R1A2A1A05079297).

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1039/c8sc04581j

Cite this

@article{7eb0d2c14e934dcfb4067242910d61e7,

title = "Fine-tuning of wettability in a single metal-organic framework: Via postcoordination modification and its reduced graphene oxide aerogel for oil-water separation",

abstract = "Elaborate control of wettability in a single platform is essential for materials' applications towards oil-water separation, but it still remains challenging. Herein, we performed postcoordination modification of Mg2(dobpdc) with monoamines of various alkyl chain lengths, enabling both long-term hydrolytic stability and facile fine-tuning of wettability. An efficient separation of oil-water mixtures was achieved by using the octylamine-appended framework (OctA). We also prepared an OctA/reduced graphene oxide aerogel that showed exceptional absorption capacities towards organic solvents and oil as well as superb recyclability with maintained absorbency.",

author = "Sunhwi Eom and Kang, {Dong Won} and Minjung Kang and Choe, {Jong Hyeak} and Hyojin Kim and Kim, {Dae Won} and Hong, {Chang Seop}",

note = "Funding Information: This work was supported by a Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT, & Future Planning (MSIP)) (NRF-2012-0008901) and by the Basic Science Research Program (NRF-2018R1A2A1A05079297). Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8sc04581j",

language = "English",

volume = "10",

pages = "2663--2669",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Fine-tuning of wettability in a single metal-organic framework

T2 - Via postcoordination modification and its reduced graphene oxide aerogel for oil-water separation

AU - Eom, Sunhwi

AU - Kang, Dong Won

AU - Kang, Minjung

AU - Choe, Jong Hyeak

AU - Kim, Hyojin

AU - Kim, Dae Won

AU - Hong, Chang Seop

N1 - Funding Information: This work was supported by a Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT, & Future Planning (MSIP)) (NRF-2012-0008901) and by the Basic Science Research Program (NRF-2018R1A2A1A05079297). Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Elaborate control of wettability in a single platform is essential for materials' applications towards oil-water separation, but it still remains challenging. Herein, we performed postcoordination modification of Mg2(dobpdc) with monoamines of various alkyl chain lengths, enabling both long-term hydrolytic stability and facile fine-tuning of wettability. An efficient separation of oil-water mixtures was achieved by using the octylamine-appended framework (OctA). We also prepared an OctA/reduced graphene oxide aerogel that showed exceptional absorption capacities towards organic solvents and oil as well as superb recyclability with maintained absorbency.

AB - Elaborate control of wettability in a single platform is essential for materials' applications towards oil-water separation, but it still remains challenging. Herein, we performed postcoordination modification of Mg2(dobpdc) with monoamines of various alkyl chain lengths, enabling both long-term hydrolytic stability and facile fine-tuning of wettability. An efficient separation of oil-water mixtures was achieved by using the octylamine-appended framework (OctA). We also prepared an OctA/reduced graphene oxide aerogel that showed exceptional absorption capacities towards organic solvents and oil as well as superb recyclability with maintained absorbency.

UR - http://www.scopus.com/inward/record.url?scp=85062236152&partnerID=8YFLogxK

U2 - 10.1039/c8sc04581j

DO - 10.1039/c8sc04581j

M3 - Article

AN - SCOPUS:85062236152

SN - 2041-6520

VL - 10

SP - 2663

EP - 2669

JO - Chemical Science

JF - Chemical Science

IS - 9

ER -

Fine-tuning of wettability in a single metal-organic framework: Via postcoordination modification and its reduced graphene oxide aerogel for oil-water separation

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this