First hyperpolarizabilities of dipolar, bis-dipolar, and octupolar molecules

Si Kyung Yang, Hyun Cheol Ahn, Seung Joon Jeon, Inge Asselberghs, Koen Clays, André Persoons, Bong Rae Cho

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

A series of dipolar (1), bis-dipolar (2), and octupolar molecules (3) containing 1, 2, and 6 dipolar units within a molecule has been synthesized and their hyperpolarizabilities were analyzed. The βHRS increases in the order, 1 < 2 < 3. The 'monomeric' βzzz increases by approximately twofold from 1 to 2, whereas βzzz of 2 and βxxx of 3 are similar. Noteworthy is the parallel increase in the hyperpolarizability tensor with the λmax.

Original languageEnglish
Pages (from-to)68-71
Number of pages4
JournalChemical Physics Letters
Volume403
Issue number1-3
DOIs
Publication statusPublished - 2005 Feb 14

Bibliographical note

Funding Information:
This work was supported by NRL-MOST and CRM-KOSEF. S.K.Y. and H.C.A. were supported by BK21 program.

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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