TY - JOUR
T1 - Flexible electrochromic and thermochromic hybrid smart window based on a highly durable ITO/graphene transparent electrode
AU - Lee, Sang Jin
AU - Lee, Sun Hee
AU - Kang, Hyung Won
AU - Nahm, Sahn
AU - Kim, Bong Hoon
AU - Kim, Hyeongkeun
AU - Han, Seung Ho
N1 - Funding Information:
This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20182020109430 ), and by Creative Materials Discovery Program and Material Innovation Leading Project through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT ( 2020M3D1A2101136 and 2020M3H4A3081879 ).
Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2021/7/15
Y1 - 2021/7/15
N2 - A flexible smart window with electrochromic (EC) and thermochromic (TC) properties is fabricated on a highly durable transparent indium-tin oxide (ITO)/graphene/polyethylene terephthalate (PET) electrode. An amorphous WO3 film and crystalline VO2 film are used as the EC and TC material, respectively, in the device. The ITO film deposited via atomic layer deposition acts as a protective layer and suppresses the plasma-induced damage of graphene, which typically occurs during the sputtering process. In this device, the amorphous WO3 film undergoes cathodic electrochromic reactions with high coloration efficiency, while the crystalline VO2 film shows characteristic thermochromic behavior. Thus, the flexible EC–TC hybrid smart window shows the controlled transmission of optical and solar energies according to the surrounding temperature and the applied voltage, allowing selective modulation of the visible and near-infrared light. The flexible EC–TC hybrid device is also very stable under mechanical bending, owing to the robust adhesion of the ITO film on the graphene support and the reduced plasma-induced damage of graphene. The fabricated high-performance, durable ITO/graphene/PET transparent electrode can pave the way for next-generation flexible optoelectronic devices as well as multifunctional flexible smart windows.
AB - A flexible smart window with electrochromic (EC) and thermochromic (TC) properties is fabricated on a highly durable transparent indium-tin oxide (ITO)/graphene/polyethylene terephthalate (PET) electrode. An amorphous WO3 film and crystalline VO2 film are used as the EC and TC material, respectively, in the device. The ITO film deposited via atomic layer deposition acts as a protective layer and suppresses the plasma-induced damage of graphene, which typically occurs during the sputtering process. In this device, the amorphous WO3 film undergoes cathodic electrochromic reactions with high coloration efficiency, while the crystalline VO2 film shows characteristic thermochromic behavior. Thus, the flexible EC–TC hybrid smart window shows the controlled transmission of optical and solar energies according to the surrounding temperature and the applied voltage, allowing selective modulation of the visible and near-infrared light. The flexible EC–TC hybrid device is also very stable under mechanical bending, owing to the robust adhesion of the ITO film on the graphene support and the reduced plasma-induced damage of graphene. The fabricated high-performance, durable ITO/graphene/PET transparent electrode can pave the way for next-generation flexible optoelectronic devices as well as multifunctional flexible smart windows.
KW - Atomic layer deposition
KW - Electrochromic materials
KW - Flexible smart windows
KW - Graphene
KW - Thermochromic materials
KW - Transparent electrodes
UR - http://www.scopus.com/inward/record.url?scp=85101957900&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2021.129028
DO - 10.1016/j.cej.2021.129028
M3 - Article
AN - SCOPUS:85101957900
SN - 1385-8947
VL - 416
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
M1 - 129028
ER -