Formation of n-type MoO3 interlayer from a solution processable aprotic solvent-based molybdenum-peroxide precursor and its application to electron transport bilayer for efficient perovskite solar cells

Min Jeong Ki; Hyong Joon Lee; Jin Kyoung Park; Jin Hyuck Heo; Sang Hyuk Im

doi:10.1016/j.cej.2023.142302

Formation of n-type MoO₃ interlayer from a solution processable aprotic solvent-based molybdenum-peroxide precursor and its application to electron transport bilayer for efficient perovskite solar cells

Min Jeong Ki
, Hyong Joon Lee
, Jin Kyoung Park
, Jin Hyuck Heo^*
, Sang Hyuk Im

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

An n-type MoO₃ thin film was prepared for the first time with solution processable Mo-peroxo (Molybdenum-peroxide ligand) strategy. An aprotic solvent is chosen as an alternative to conventional protic alcoholic diluents for the Mo-peroxo precursor. The proton-donating nature of protic solvents induces gap states to form hole-selective H_xMoO₃ films, while the absence of proton donors in aprotic solvents facilitates n-type MoO₃ thin films by a solution process. The aprotic diluent-based thin film is identified as a peroxy structure at low temperatures and is successfully converted to n-type MoO₃ through the removal of peroxide ligands during thermal annealing. Finally, we implement the n-type MoO₃ thin film as an inorganic electron transport bilayer paired with SnO₂ for (FAPbI₃)_0.95(MAPbBr₃)_0.05 perovskite solar cells. The n-type MoO₃ interlayer increases the conductivity of the combined n-type MoO₃/SnO₂ electron transport bilayer, which improves the charge carrier extraction and transport properties. The prepared perovskite solar cell exhibits enhanced power conversion efficiency (PCE) reaching 23.82 % along with a remarkable open-circuit voltage (V_OC) of 1.16 V.

Original language	English
Article number	142302
Journal	Chemical Engineering Journal
Volume	462
DOIs	https://doi.org/10.1016/j.cej.2023.142302
Publication status	Published - 2023 Apr 15

Bibliographical note

Funding Information:
M.J. Ki and H.J. Lee have equally contributed to this work. This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT & Future Planning (Basic Science Research Program [Grant No. 2021R1A5A6002853], [Grant No. 2022R1A2C3004964], [Grant No. 2022R1C1C2008126], [Grant No. 2022M3H4A1A03074093]) and by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) under the Ministry of Trade, Industry & Energy (MOTIE) [Grant No. 20227410100040].

Publisher Copyright:
© 2023 Elsevier B.V.

Keywords

Electron transport layer
Homovalent
Molybdenum oxide
Perovskite solar cell
Solution process

ASJC Scopus subject areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

Access to Document

10.1016/j.cej.2023.142302

Cite this

Formation of n-type MoO₃ interlayer from a solution processable aprotic solvent-based molybdenum-peroxide precursor and its application to electron transport bilayer for efficient perovskite solar cells. / Ki, Min Jeong; Lee, Hyong Joon; Park, Jin Kyoung et al.
In: Chemical Engineering Journal, Vol. 462, 142302, 15.04.2023.

Research output: Contribution to journal › Article › peer-review

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title = "Formation of n-type MoO3 interlayer from a solution processable aprotic solvent-based molybdenum-peroxide precursor and its application to electron transport bilayer for efficient perovskite solar cells",

abstract = "An n-type MoO3 thin film was prepared for the first time with solution processable Mo-peroxo (Molybdenum-peroxide ligand) strategy. An aprotic solvent is chosen as an alternative to conventional protic alcoholic diluents for the Mo-peroxo precursor. The proton-donating nature of protic solvents induces gap states to form hole-selective HxMoO3 films, while the absence of proton donors in aprotic solvents facilitates n-type MoO3 thin films by a solution process. The aprotic diluent-based thin film is identified as a peroxy structure at low temperatures and is successfully converted to n-type MoO3 through the removal of peroxide ligands during thermal annealing. Finally, we implement the n-type MoO3 thin film as an inorganic electron transport bilayer paired with SnO2 for (FAPbI3)0.95(MAPbBr3)0.05 perovskite solar cells. The n-type MoO3 interlayer increases the conductivity of the combined n-type MoO3/SnO2 electron transport bilayer, which improves the charge carrier extraction and transport properties. The prepared perovskite solar cell exhibits enhanced power conversion efficiency (PCE) reaching 23.82 \% along with a remarkable open-circuit voltage (VOC) of 1.16 V.",

keywords = "Electron transport layer, Homovalent, Molybdenum oxide, Perovskite solar cell, Solution process",

author = "Ki, \{Min Jeong\} and Lee, \{Hyong Joon\} and Park, \{Jin Kyoung\} and Heo, \{Jin Hyuck\} and Im, \{Sang Hyuk\}",

note = "Funding Information: M.J. Ki and H.J. Lee have equally contributed to this work. This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT \& Future Planning (Basic Science Research Program [Grant No. 2021R1A5A6002853], [Grant No. 2022R1A2C3004964], [Grant No. 2022R1C1C2008126], [Grant No. 2022M3H4A1A03074093]) and by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) under the Ministry of Trade, Industry \& Energy (MOTIE) [Grant No. 20227410100040]. Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

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T1 - Formation of n-type MoO3 interlayer from a solution processable aprotic solvent-based molybdenum-peroxide precursor and its application to electron transport bilayer for efficient perovskite solar cells

AU - Ki, Min Jeong

AU - Lee, Hyong Joon

AU - Park, Jin Kyoung

AU - Heo, Jin Hyuck

AU - Im, Sang Hyuk

N1 - Funding Information: M.J. Ki and H.J. Lee have equally contributed to this work. This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT & Future Planning (Basic Science Research Program [Grant No. 2021R1A5A6002853], [Grant No. 2022R1A2C3004964], [Grant No. 2022R1C1C2008126], [Grant No. 2022M3H4A1A03074093]) and by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) under the Ministry of Trade, Industry & Energy (MOTIE) [Grant No. 20227410100040]. Publisher Copyright: © 2023 Elsevier B.V.

PY - 2023/4/15

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N2 - An n-type MoO3 thin film was prepared for the first time with solution processable Mo-peroxo (Molybdenum-peroxide ligand) strategy. An aprotic solvent is chosen as an alternative to conventional protic alcoholic diluents for the Mo-peroxo precursor. The proton-donating nature of protic solvents induces gap states to form hole-selective HxMoO3 films, while the absence of proton donors in aprotic solvents facilitates n-type MoO3 thin films by a solution process. The aprotic diluent-based thin film is identified as a peroxy structure at low temperatures and is successfully converted to n-type MoO3 through the removal of peroxide ligands during thermal annealing. Finally, we implement the n-type MoO3 thin film as an inorganic electron transport bilayer paired with SnO2 for (FAPbI3)0.95(MAPbBr3)0.05 perovskite solar cells. The n-type MoO3 interlayer increases the conductivity of the combined n-type MoO3/SnO2 electron transport bilayer, which improves the charge carrier extraction and transport properties. The prepared perovskite solar cell exhibits enhanced power conversion efficiency (PCE) reaching 23.82 % along with a remarkable open-circuit voltage (VOC) of 1.16 V.

AB - An n-type MoO3 thin film was prepared for the first time with solution processable Mo-peroxo (Molybdenum-peroxide ligand) strategy. An aprotic solvent is chosen as an alternative to conventional protic alcoholic diluents for the Mo-peroxo precursor. The proton-donating nature of protic solvents induces gap states to form hole-selective HxMoO3 films, while the absence of proton donors in aprotic solvents facilitates n-type MoO3 thin films by a solution process. The aprotic diluent-based thin film is identified as a peroxy structure at low temperatures and is successfully converted to n-type MoO3 through the removal of peroxide ligands during thermal annealing. Finally, we implement the n-type MoO3 thin film as an inorganic electron transport bilayer paired with SnO2 for (FAPbI3)0.95(MAPbBr3)0.05 perovskite solar cells. The n-type MoO3 interlayer increases the conductivity of the combined n-type MoO3/SnO2 electron transport bilayer, which improves the charge carrier extraction and transport properties. The prepared perovskite solar cell exhibits enhanced power conversion efficiency (PCE) reaching 23.82 % along with a remarkable open-circuit voltage (VOC) of 1.16 V.

KW - Electron transport layer

KW - Homovalent

KW - Molybdenum oxide

KW - Perovskite solar cell

KW - Solution process

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