Fourier-transform infrared spectroscopy of hopping oscillations of electrons in vanadium oxide nanotubes

Min Ha Oh, Hyo Jung Kim, Kyu Won Lee, Cheol Eui Lee

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

We have employed Fourier-transform infrared spectroscopy in order to study the phase transitions and charge dynamics in vanadium oxide nanotubes with alternating organic and inorganic layers. The structural phase transitions accompanied by conformational changes in the organic layer were identified. Besides, a phase transition around 343 K from an insulator phase to a metal-like one that arises from electron delocalization was observed in the inorganic layers, manifesting an electron hopping oscillation between the V4+ and V5+ sites.

Original languageEnglish
Article number113105
JournalApplied Physics Letters
Volume102
Issue number11
DOIs
Publication statusPublished - 2013 Mar 18

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

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