Gloss reduction and morphological properties of polycarbonate and poly(methyl methacrylate-acrylonitrile-butadiene-styrene) blends with SAN-co-GMA as a reactive compatibilizer

In Chol Kim, Kee Hae Kwon, Woo Nyon Kim

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The gloss properties of the polycarbonate (PC)/poly(methyl methacrylate-acrylonitrile-butadiene-styrene) (MABS) blend with styrene-acrylonitrile-co-glycidyl methacrylate (SAN-co-GMA) as a compatibilizing agent were investigated. For the PC/poly(MABS)/SAN-co-GMA (65/15/20, wt %) blend surface, the reduction of gloss level was observed most significantly when the GMA content was 0.1 wt %, compared with the blends with 0.05 wt % GMA or without GMA content. The gloss level of the PC/poly(MABS)/SAN-co-GMA (0.1 wt % GMA) blend surface was observed to be 35, which showed 65% lower than the PC/poly(MABS)/SAN-co-GMA blend without GMA content. The gloss reduction was most probably caused by the insoluble fractions of the PC/poly(MABS)/SAN-co-GMA blend that were formed by the reaction between the carboxylic acid group in poly(MABS) and epoxy group in SAN-co-GMA. The results of optical and transmission electron microscope analysis, spectroscopy study, and rheological properties supported the formation of insoluble structure of the PC/poly(MABS)/SAN-co-GMA blend when the GMA content was 0.1 wt %.

Original languageEnglish
Article number46450
JournalJournal of Applied Polymer Science
Volume135
Issue number27
DOIs
Publication statusPublished - 2018 Jul 15

Bibliographical note

Publisher Copyright:
© 2018 Wiley Periodicals, Inc.

Keywords

  • compatibilization
  • extrusion
  • optical properties
  • structure–property relationships

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • General Chemistry
  • Polymers and Plastics

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