H-bond switching and ligand exchange dynamics in aqueous ionic solution

Kelly J. Gaffney; Minbiao Ji; Michael Odelius; Sungnam Park; Zheng Sun

doi:10.1016/j.cplett.2011.01.063

H-bond switching and ligand exchange dynamics in aqueous ionic solution

Kelly J. Gaffney
, Minbiao Ji
, Michael Odelius
, Sungnam Park
, Zheng Sun

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Aqueous ionic solutions lubricate the chemical machinery of the environment and life. Understanding the impact of ions on the properties of aqueous solutions and how these modified properties influence chemical and conformational dynamics remains an important and elusive objective of physical chemistry research. Here we discuss recent advances in our understanding that have been derived from ultrafast vibrational spectroscopy and molecular dynamics simulations.

Original language	English
Pages (from-to)	1-6
Number of pages	6
Journal	Chemical Physics Letters
Volume	504
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2011.01.063
Publication status	Published - 2011 Feb 28

Bibliographical note

Funding Information:
K.G., M.J., and Z.S. acknowledge salary and equipment support through the PULSE Institute at SLAC National Accelerator Laboratory by the US Department of Energy, Office of Basic Energy Sciences. M.O. thanks the Swedish Research Council (VR), the Carl Trygger foundation, and the Magnus Bergvall foundation for support and gratefully acknowledges generous grants of computer time through SNIC at the Swedish National Supercomputer Center (NSC) and Center for Parallel Computing (PDC).

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2011.01.063

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title = "H-bond switching and ligand exchange dynamics in aqueous ionic solution",

abstract = "Aqueous ionic solutions lubricate the chemical machinery of the environment and life. Understanding the impact of ions on the properties of aqueous solutions and how these modified properties influence chemical and conformational dynamics remains an important and elusive objective of physical chemistry research. Here we discuss recent advances in our understanding that have been derived from ultrafast vibrational spectroscopy and molecular dynamics simulations.",

author = "Gaffney, \{Kelly J.\} and Minbiao Ji and Michael Odelius and Sungnam Park and Zheng Sun",

note = "Funding Information: K.G., M.J., and Z.S. acknowledge salary and equipment support through the PULSE Institute at SLAC National Accelerator Laboratory by the US Department of Energy, Office of Basic Energy Sciences. M.O. thanks the Swedish Research Council (VR), the Carl Trygger foundation, and the Magnus Bergvall foundation for support and gratefully acknowledges generous grants of computer time through SNIC at the Swedish National Supercomputer Center (NSC) and Center for Parallel Computing (PDC). ",

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doi = "10.1016/j.cplett.2011.01.063",

language = "English",

volume = "504",

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T1 - H-bond switching and ligand exchange dynamics in aqueous ionic solution

AU - Gaffney, Kelly J.

AU - Ji, Minbiao

AU - Odelius, Michael

AU - Park, Sungnam

AU - Sun, Zheng

N1 - Funding Information: K.G., M.J., and Z.S. acknowledge salary and equipment support through the PULSE Institute at SLAC National Accelerator Laboratory by the US Department of Energy, Office of Basic Energy Sciences. M.O. thanks the Swedish Research Council (VR), the Carl Trygger foundation, and the Magnus Bergvall foundation for support and gratefully acknowledges generous grants of computer time through SNIC at the Swedish National Supercomputer Center (NSC) and Center for Parallel Computing (PDC).

PY - 2011/2/28

Y1 - 2011/2/28

N2 - Aqueous ionic solutions lubricate the chemical machinery of the environment and life. Understanding the impact of ions on the properties of aqueous solutions and how these modified properties influence chemical and conformational dynamics remains an important and elusive objective of physical chemistry research. Here we discuss recent advances in our understanding that have been derived from ultrafast vibrational spectroscopy and molecular dynamics simulations.

AB - Aqueous ionic solutions lubricate the chemical machinery of the environment and life. Understanding the impact of ions on the properties of aqueous solutions and how these modified properties influence chemical and conformational dynamics remains an important and elusive objective of physical chemistry research. Here we discuss recent advances in our understanding that have been derived from ultrafast vibrational spectroscopy and molecular dynamics simulations.

UR - https://www.scopus.com/pages/publications/79952009715

U2 - 10.1016/j.cplett.2011.01.063

DO - 10.1016/j.cplett.2011.01.063

M3 - Article

AN - SCOPUS:79952009715

SN - 0009-2614

VL - 504

SP - 1

EP - 6

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

H-bond switching and ligand exchange dynamics in aqueous ionic solution

Abstract

Bibliographical note

ASJC Scopus subject areas

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