Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Choong Eui Song; Jung Woon Yang; Eun Joo Roh; Sang Gi Lee; Jou Hyeon Ahn; Hogyu Han

doi:10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Choong Eui Song^*
, Jung Woon Yang
, Eun Joo Roh
, Sang Gi Lee
, Jou Hyeon Ahn
, Hogyu Han

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η³-C₃H₅)PdCl}₂] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

Original language	English
Pages (from-to)	3852-3854
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	20
DOIs	https://doi.org/10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
Publication status	Published - 2002 Oct 18

Keywords

Asymmetric catalysis
Heterogeneous catalysis
P ligands
Palladium
Polymers

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

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title = "Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands",

abstract = "Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [\{(η3-C3H5)PdCl\}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99\% ee).",

keywords = "Asymmetric catalysis, Heterogeneous catalysis, P ligands, Palladium, Polymers",

author = "Song, \{Choong Eui\} and Yang, \{Jung Woon\} and Roh, \{Eun Joo\} and Lee, \{Sang Gi\} and Ahn, \{Jou Hyeon\} and Hogyu Han",

year = "2002",

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doi = "10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I",

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T1 - Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

AU - Song, Choong Eui

AU - Yang, Jung Woon

AU - Roh, Eun Joo

AU - Lee, Sang Gi

AU - Ahn, Jou Hyeon

AU - Han, Hogyu

PY - 2002/10/18

Y1 - 2002/10/18

N2 - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

AB - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

KW - Asymmetric catalysis

KW - Heterogeneous catalysis

KW - P ligands

KW - Palladium

KW - Polymers

UR - https://www.scopus.com/pages/publications/0037131591

U2 - 10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

DO - 10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

M3 - Article

C2 - 12386868

AN - SCOPUS:0037131591

SN - 1433-7851

VL - 41

SP - 3852

EP - 3854

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 20

ER -

Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Abstract

Keywords

ASJC Scopus subject areas

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