High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer

Jin Hyuck Heo; Min Hyuk Jang; Min Ho Lee; Dong Hee Shin; Do Hun Kim; Sang Hwa Moon; Sang Wook Kim; Bum Jun Park; Sang Hyuk Im

doi:10.1021/acsami.7b12046

High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer

Jin Hyuck Heo
, Min Hyuk Jang
, Min Ho Lee
, Dong Hee Shin
, Do Hun Kim
, Sang Hwa Moon
, Sang Wook Kim
, Bum Jun Park^*
, Sang Hyuk Im

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

High-performance solid-state PbS quantum dot-sensitized solar cells (QD-SSCs) with stable 9.2% power conversion efficiency at 1 Sun condition are demonstrated by introduction of hybrid perovskite interlayer. The PbS QDs formed on mesoscopic TiO₂ (mp-TiO₂) by spin-assisted successive precipitation and anionic exchange reaction method do not exhibit PbSO₄ but have PbSO₃ oxidation species. By introducing perovskite interlayer in between mp-TiO₂/PbS QDs and poly-3-hexylthiophene, the PbSO₃ oxidation species are fully removed in the PbS QDs and thereby the efficiency of PbS QD-SSCs is enhanced over 90% compared to the pristine PbS QD-SSCs.

Original language	English
Pages (from-to)	41104-41110
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	9
Issue number	47
DOIs	https://doi.org/10.1021/acsami.7b12046
Publication status	Published - 2017 Nov 29

Bibliographical note

Publisher Copyright:
© 2017 American Chemical Society.

Keywords

lead sulfide
passivation
perovskite
quantum dots
sensitized solar cells

ASJC Scopus subject areas

General Materials Science

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10.1021/acsami.7b12046

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@article{965dc4a67b9444e596821380f78c1080,

title = "High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer",

abstract = "High-performance solid-state PbS quantum dot-sensitized solar cells (QD-SSCs) with stable 9.2\% power conversion efficiency at 1 Sun condition are demonstrated by introduction of hybrid perovskite interlayer. The PbS QDs formed on mesoscopic TiO2 (mp-TiO2) by spin-assisted successive precipitation and anionic exchange reaction method do not exhibit PbSO4 but have PbSO3 oxidation species. By introducing perovskite interlayer in between mp-TiO2/PbS QDs and poly-3-hexylthiophene, the PbSO3 oxidation species are fully removed in the PbS QDs and thereby the efficiency of PbS QD-SSCs is enhanced over 90\% compared to the pristine PbS QD-SSCs.",

keywords = "lead sulfide, passivation, perovskite, quantum dots, sensitized solar cells",

author = "Heo, \{Jin Hyuck\} and Jang, \{Min Hyuk\} and Lee, \{Min Ho\} and Shin, \{Dong Hee\} and Kim, \{Do Hun\} and Moon, \{Sang Hwa\} and Kim, \{Sang Wook\} and Park, \{Bum Jun\} and Im, \{Sang Hyuk\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = nov,

day = "29",

doi = "10.1021/acsami.7b12046",

language = "English",

volume = "9",

pages = "41104--41110",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

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TY - JOUR

T1 - High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer

AU - Heo, Jin Hyuck

AU - Jang, Min Hyuk

AU - Lee, Min Ho

AU - Shin, Dong Hee

AU - Kim, Do Hun

AU - Moon, Sang Hwa

AU - Kim, Sang Wook

AU - Park, Bum Jun

AU - Im, Sang Hyuk

PY - 2017/11/29

Y1 - 2017/11/29

N2 - High-performance solid-state PbS quantum dot-sensitized solar cells (QD-SSCs) with stable 9.2% power conversion efficiency at 1 Sun condition are demonstrated by introduction of hybrid perovskite interlayer. The PbS QDs formed on mesoscopic TiO2 (mp-TiO2) by spin-assisted successive precipitation and anionic exchange reaction method do not exhibit PbSO4 but have PbSO3 oxidation species. By introducing perovskite interlayer in between mp-TiO2/PbS QDs and poly-3-hexylthiophene, the PbSO3 oxidation species are fully removed in the PbS QDs and thereby the efficiency of PbS QD-SSCs is enhanced over 90% compared to the pristine PbS QD-SSCs.

AB - High-performance solid-state PbS quantum dot-sensitized solar cells (QD-SSCs) with stable 9.2% power conversion efficiency at 1 Sun condition are demonstrated by introduction of hybrid perovskite interlayer. The PbS QDs formed on mesoscopic TiO2 (mp-TiO2) by spin-assisted successive precipitation and anionic exchange reaction method do not exhibit PbSO4 but have PbSO3 oxidation species. By introducing perovskite interlayer in between mp-TiO2/PbS QDs and poly-3-hexylthiophene, the PbSO3 oxidation species are fully removed in the PbS QDs and thereby the efficiency of PbS QD-SSCs is enhanced over 90% compared to the pristine PbS QD-SSCs.

KW - lead sulfide

KW - passivation

KW - perovskite

KW - quantum dots

KW - sensitized solar cells

UR - https://www.scopus.com/pages/publications/85036464141

U2 - 10.1021/acsami.7b12046

DO - 10.1021/acsami.7b12046

M3 - Article

C2 - 29134800

AN - SCOPUS:85036464141

SN - 1944-8244

VL - 9

SP - 41104

EP - 41110

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 47

ER -

High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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