Higher Quantum State Transitions in Colloidal Quantum Dot with Heavy Electron Doping

Bitna Yoon, Juyeon Jeong, Kwang Seob Jeong

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)


Electron occupation in the lowest quantized state of the conduction band (1Se) in the colloidal quantum dot leads to the intraband transition in steady-state (1Se-1Pe). The intraband transition, solely originating from the quantum confinement effect, is the unique property of semiconducting nanocrystals. To achieve the electron occupation in 1Se state in the absence of impurity ions, nonthiol ligand passivated HgS colloidal quantum dots are synthesized. The nonthiol ligand passivated HgS quantum dot exhibits strong steady-state intraband transition in ambient condition and enables a versatile ligand replacement to oxide, acid, and halide functional ligands, which was not achievable from conventional HgS or HgSe quantum dots. Surprisingly, the atomic ligand passivation to HgS colloidal quantum dot solution efficiently maintains the electron occupation at 1Se of HgS CQDs in ambient condition. The electron occupation in 1Se of HgS CQD solid film is controlled by surface treatment with charged ions, which is confirmed by the mid-IR intraband absorption (1Se-1Pe) intensity imaged by the FTIR microscope. Furthermore, a novel second intraband transition (1Pe-1De) is observed from the HgS CQD solid. The observation of the second intraband transition (1Pe-De) allows us to utilize the higher quantized states that were hidden for the last three decades. The use of the intraband transition with narrow bandwidth in mid-IR would enable to choose an optimal electronic transition occurring in the nanocrystal for a number of applications: wavelength-selective low-energy consuming electronics, space-communication light source, mid-infrared energy sensitized electrode and catalyst, infrared photodetector, and infrared filter.

Original languageEnglish
Pages (from-to)22062-22068
Number of pages7
JournalJournal of Physical Chemistry C
Issue number38
Publication statusPublished - 2016 Sept 29

Bibliographical note

Funding Information:
This work is supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, & Future Planning (NRF-2016R1C1B2013416) and the Ministry of Education (NRF20100020209). The authors used the facilities in the institute and companies (Korea Basic Science Institute Seoul Center, Scinco, PerkinElmer Korea).

Publisher Copyright:
© 2016 American Chemical Society.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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