Highly stretchable white-light electroluminescent devices with gel-type silica-coated all-inorganic perovskite

Sang Yeop Lee; Sanghyun Jeon; Junhyuk Ahn; Junsung Bang; Ho Kun Woo; Kyu joon Lee; Byung Ku Jung; Taesung Park; Donghee Son; Jae Pyoung Ahn; Soong Ju Oh

doi:10.1016/j.apsusc.2021.150229

Highly stretchable white-light electroluminescent devices with gel-type silica-coated all-inorganic perovskite

Sang Yeop Lee, Sanghyun Jeon, Junhyuk Ahn, Junsung Bang, Ho Kun Woo, Kyu joon Lee, Byung Ku Jung, Taesung Park, Donghee Son, Jae Pyoung Ahn, Soong Ju Oh

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

In this study, a highly stretchable white-light electroluminescent device is fabricated using chemically designed perovskite nanocrystals (NCs). To incorporate perovskite into a stretchable polymer matrix without any degradation, gel-type silica-coated CsPbBr₃ and CsPbBr_xI_3-x NC inks are prepared using (3-aminopropyl) triethoxysilane (APTES) with a sacrificial solvent of hexane. The chemical, optical, and structural properties of powdered and gel-type perovskite NCs with and without APTES are investigated. Silica shell with APTES treatment improves the stability of perovskite NCs, and gel-type inks improve the dispersivity in the polymer matrix. These enable the fabrication of stretchable and luminescent NC/polymer matrices with enhanced and uniform luminescence properties. By utilizing these materials, we propose a stretchable electroluminescent device emitting strong white light that is close to the ideal white position in Commission Internationale de l'éclairage (CIE) with optical simulation. Herein, we fabricate a multi-color filter with high color reproducibility on stretchable blue electroluminescent devices for white-light generation. Furthermore, all-solution-processed, color-filterless, stretchable, white-light electroluminescence devices with excellent optical and mechanical properties are fabricated.

Original language	English
Article number	150229
Journal	Applied Surface Science
Volume	563
DOIs	https://doi.org/10.1016/j.apsusc.2021.150229
Publication status	Published - 2021 Oct 15

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2019R1C1C1003319), and Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (NRF-2018M3D1A1059001). This work is also supported by the Materials Innovation Project (NRF-2021M3H4A3026733) through the National Research Foundation of Korea (NRF), and by a Korea University Grant.

Publisher Copyright:
© 2021

Keywords

Cesium lead halide perovskite
Stretchable device
Surface chemistry
Surface modification
White light

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces, Coatings and Films
Surfaces and Interfaces

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10.1016/j.apsusc.2021.150229

Cite this

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title = "Highly stretchable white-light electroluminescent devices with gel-type silica-coated all-inorganic perovskite",

abstract = "In this study, a highly stretchable white-light electroluminescent device is fabricated using chemically designed perovskite nanocrystals (NCs). To incorporate perovskite into a stretchable polymer matrix without any degradation, gel-type silica-coated CsPbBr3 and CsPbBrxI3-x NC inks are prepared using (3-aminopropyl) triethoxysilane (APTES) with a sacrificial solvent of hexane. The chemical, optical, and structural properties of powdered and gel-type perovskite NCs with and without APTES are investigated. Silica shell with APTES treatment improves the stability of perovskite NCs, and gel-type inks improve the dispersivity in the polymer matrix. These enable the fabrication of stretchable and luminescent NC/polymer matrices with enhanced and uniform luminescence properties. By utilizing these materials, we propose a stretchable electroluminescent device emitting strong white light that is close to the ideal white position in Commission Internationale de l'{\'e}clairage (CIE) with optical simulation. Herein, we fabricate a multi-color filter with high color reproducibility on stretchable blue electroluminescent devices for white-light generation. Furthermore, all-solution-processed, color-filterless, stretchable, white-light electroluminescence devices with excellent optical and mechanical properties are fabricated.",

keywords = "Cesium lead halide perovskite, Stretchable device, Surface chemistry, Surface modification, White light",

author = "Lee, {Sang Yeop} and Sanghyun Jeon and Junhyuk Ahn and Junsung Bang and Woo, {Ho Kun} and Lee, {Kyu joon} and Jung, {Byung Ku} and Taesung Park and Donghee Son and Ahn, {Jae Pyoung} and Oh, {Soong Ju}",

note = "Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2019R1C1C1003319), and Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (NRF-2018M3D1A1059001). This work is also supported by the Materials Innovation Project (NRF-2021M3H4A3026733) through the National Research Foundation of Korea (NRF), and by a Korea University Grant. Publisher Copyright: {\textcopyright} 2021",

year = "2021",

month = oct,

day = "15",

doi = "10.1016/j.apsusc.2021.150229",

language = "English",

volume = "563",

journal = "Applied Surface Science",

issn = "0169-4332",

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T1 - Highly stretchable white-light electroluminescent devices with gel-type silica-coated all-inorganic perovskite

AU - Lee, Sang Yeop

AU - Jeon, Sanghyun

AU - Ahn, Junhyuk

AU - Bang, Junsung

AU - Woo, Ho Kun

AU - Lee, Kyu joon

AU - Jung, Byung Ku

AU - Park, Taesung

AU - Son, Donghee

AU - Ahn, Jae Pyoung

AU - Oh, Soong Ju

N1 - Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2019R1C1C1003319), and Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (NRF-2018M3D1A1059001). This work is also supported by the Materials Innovation Project (NRF-2021M3H4A3026733) through the National Research Foundation of Korea (NRF), and by a Korea University Grant. Publisher Copyright: © 2021

PY - 2021/10/15

Y1 - 2021/10/15

N2 - In this study, a highly stretchable white-light electroluminescent device is fabricated using chemically designed perovskite nanocrystals (NCs). To incorporate perovskite into a stretchable polymer matrix without any degradation, gel-type silica-coated CsPbBr3 and CsPbBrxI3-x NC inks are prepared using (3-aminopropyl) triethoxysilane (APTES) with a sacrificial solvent of hexane. The chemical, optical, and structural properties of powdered and gel-type perovskite NCs with and without APTES are investigated. Silica shell with APTES treatment improves the stability of perovskite NCs, and gel-type inks improve the dispersivity in the polymer matrix. These enable the fabrication of stretchable and luminescent NC/polymer matrices with enhanced and uniform luminescence properties. By utilizing these materials, we propose a stretchable electroluminescent device emitting strong white light that is close to the ideal white position in Commission Internationale de l'éclairage (CIE) with optical simulation. Herein, we fabricate a multi-color filter with high color reproducibility on stretchable blue electroluminescent devices for white-light generation. Furthermore, all-solution-processed, color-filterless, stretchable, white-light electroluminescence devices with excellent optical and mechanical properties are fabricated.

AB - In this study, a highly stretchable white-light electroluminescent device is fabricated using chemically designed perovskite nanocrystals (NCs). To incorporate perovskite into a stretchable polymer matrix without any degradation, gel-type silica-coated CsPbBr3 and CsPbBrxI3-x NC inks are prepared using (3-aminopropyl) triethoxysilane (APTES) with a sacrificial solvent of hexane. The chemical, optical, and structural properties of powdered and gel-type perovskite NCs with and without APTES are investigated. Silica shell with APTES treatment improves the stability of perovskite NCs, and gel-type inks improve the dispersivity in the polymer matrix. These enable the fabrication of stretchable and luminescent NC/polymer matrices with enhanced and uniform luminescence properties. By utilizing these materials, we propose a stretchable electroluminescent device emitting strong white light that is close to the ideal white position in Commission Internationale de l'éclairage (CIE) with optical simulation. Herein, we fabricate a multi-color filter with high color reproducibility on stretchable blue electroluminescent devices for white-light generation. Furthermore, all-solution-processed, color-filterless, stretchable, white-light electroluminescence devices with excellent optical and mechanical properties are fabricated.

KW - Cesium lead halide perovskite

KW - Stretchable device

KW - Surface chemistry

KW - Surface modification

KW - White light

UR - http://www.scopus.com/inward/record.url?scp=85108738191&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2021.150229

DO - 10.1016/j.apsusc.2021.150229

M3 - Article

AN - SCOPUS:85108738191

SN - 0169-4332

VL - 563

JO - Applied Surface Science

JF - Applied Surface Science

M1 - 150229

ER -

Highly stretchable white-light electroluminescent devices with gel-type silica-coated all-inorganic perovskite

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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