Abstract
Single-crystal-to-single crystal structural conversions occur in a Zn(ii) coordination polymer, uniquely induced by fine-tuned relative humidity. Proton conductivity depends on the number of hydrogen bonds in the structures. Slope change in the Arrhenius plot is uncommon among coordination-based conductors and associated with temperature-dependent phase changes.
Original language | English |
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Pages (from-to) | 9713-9716 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 55 |
Issue number | 65 |
DOIs | |
Publication status | Published - 2019 |
Bibliographical note
Funding Information:This work was supported by the Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT, & Future Planning (MSIP)) (NRF-2012-0008901), the Basic Science Research Program (NRF-2018R1A2A1A050 79297), the Priority Research Centers Program (NRF-2019R1A6A 1A11044070), the National Research Council of Science & Technology (NST) grant by the Korea government (MSIT) (No. CRC-14-1-KRICT), and PAL.
Publisher Copyright:
© The Royal Society of Chemistry 2019.
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry