Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications

Sungwon Kim; Donghwan Kim; Hyun Ji Kim; Yun Jae Lee; Seung Sang Hwang; Kyung Youl Baek

doi:10.4028/www.scientific.net/MSF.700.120

Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications

Sungwon Kim, Donghwan Kim, Hyun Ji Kim, Yun Jae Lee, Seung Sang Hwang, Kyung Youl Baek

Department of Materials Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

3 Citations (Scopus)

Abstract

We synthesized a new hybrid nanocomposite consisting of CdSe quantum dot (QD) and regioregular poly(3-hexylthiophene)-b-poly(N,N-dimethylamino-2- ethylmethacrylate) rod-coil block copolymer to investigate the effects of nanoscale morphology to the photovoltaic properties in inorganic-organic hybrid solar cell. Well-defined conducting rod-coil block copolymers, P3HT-b-PDMAEMA, were synthesized by combination of Grignard metathesis polymerization (GRIM) and atom transfer radical polymerization (ATRP) methods. These rod-coil block copolymers were then mixed with oleic acid capped CdSe QDs through ligand exchange and characterized their nanoscale morphology and optoelectronic properties. These results can be explained by the effects of the bicontinuous electron-donor/electron-acceptor networks in active layer based on rod-coil P3HT-b-PDMAEMA block copolymers blended with CdSe QDs.

Original language	English
Title of host publication	Advanced Materials and Nanotechnology, AMN-5
Publisher	Trans Tech Publications Ltd
Pages	120-124
Number of pages	5
ISBN (Print)	9783037852637
DOIs	https://doi.org/10.4028/www.scientific.net/MSF.700.120
Publication status	Published - 2012
Event	5th Biennial Conference on Advanced Materials and Nanotechnology, AMN-5 - Wellington, New Zealand Duration: 2011 Feb 7 → 2011 Feb 11

Publication series

Name	Materials Science Forum
Volume	700
ISSN (Print)	0255-5476
ISSN (Electronic)	1662-9752

Other

Other	5th Biennial Conference on Advanced Materials and Nanotechnology, AMN-5
Country/Territory	New Zealand
City	Wellington
Period	11/2/7 → 11/2/11

Keywords

CdSe Quantum Dots
P3HT-b-PDMAEMA
Rod-Coil Block Copolymer
Solar Cells

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.4028/www.scientific.net/MSF.700.120

Cite this

Kim, S., Kim, D., Kim, H. J., Lee, Y. J., Hwang, S. S., & Baek, K. Y. (2012). Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications. In Advanced Materials and Nanotechnology, AMN-5 (pp. 120-124). (Materials Science Forum; Vol. 700). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.700.120

Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications. / Kim, Sungwon; Kim, Donghwan; Kim, Hyun Ji et al.
Advanced Materials and Nanotechnology, AMN-5. Trans Tech Publications Ltd, 2012. p. 120-124 (Materials Science Forum; Vol. 700).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Kim, S, Kim, D, Kim, HJ, Lee, YJ, Hwang, SS & Baek, KY 2012, Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications. in Advanced Materials and Nanotechnology, AMN-5. Materials Science Forum, vol. 700, Trans Tech Publications Ltd, pp. 120-124, 5th Biennial Conference on Advanced Materials and Nanotechnology, AMN-5, Wellington, New Zealand, 11/2/7. https://doi.org/10.4028/www.scientific.net/MSF.700.120

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title = "Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications",

abstract = "We synthesized a new hybrid nanocomposite consisting of CdSe quantum dot (QD) and regioregular poly(3-hexylthiophene)-b-poly(N,N-dimethylamino-2- ethylmethacrylate) rod-coil block copolymer to investigate the effects of nanoscale morphology to the photovoltaic properties in inorganic-organic hybrid solar cell. Well-defined conducting rod-coil block copolymers, P3HT-b-PDMAEMA, were synthesized by combination of Grignard metathesis polymerization (GRIM) and atom transfer radical polymerization (ATRP) methods. These rod-coil block copolymers were then mixed with oleic acid capped CdSe QDs through ligand exchange and characterized their nanoscale morphology and optoelectronic properties. These results can be explained by the effects of the bicontinuous electron-donor/electron-acceptor networks in active layer based on rod-coil P3HT-b-PDMAEMA block copolymers blended with CdSe QDs.",

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AU - Lee, Yun Jae

AU - Hwang, Seung Sang

AU - Baek, Kyung Youl

PY - 2012

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N2 - We synthesized a new hybrid nanocomposite consisting of CdSe quantum dot (QD) and regioregular poly(3-hexylthiophene)-b-poly(N,N-dimethylamino-2- ethylmethacrylate) rod-coil block copolymer to investigate the effects of nanoscale morphology to the photovoltaic properties in inorganic-organic hybrid solar cell. Well-defined conducting rod-coil block copolymers, P3HT-b-PDMAEMA, were synthesized by combination of Grignard metathesis polymerization (GRIM) and atom transfer radical polymerization (ATRP) methods. These rod-coil block copolymers were then mixed with oleic acid capped CdSe QDs through ligand exchange and characterized their nanoscale morphology and optoelectronic properties. These results can be explained by the effects of the bicontinuous electron-donor/electron-acceptor networks in active layer based on rod-coil P3HT-b-PDMAEMA block copolymers blended with CdSe QDs.

AB - We synthesized a new hybrid nanocomposite consisting of CdSe quantum dot (QD) and regioregular poly(3-hexylthiophene)-b-poly(N,N-dimethylamino-2- ethylmethacrylate) rod-coil block copolymer to investigate the effects of nanoscale morphology to the photovoltaic properties in inorganic-organic hybrid solar cell. Well-defined conducting rod-coil block copolymers, P3HT-b-PDMAEMA, were synthesized by combination of Grignard metathesis polymerization (GRIM) and atom transfer radical polymerization (ATRP) methods. These rod-coil block copolymers were then mixed with oleic acid capped CdSe QDs through ligand exchange and characterized their nanoscale morphology and optoelectronic properties. These results can be explained by the effects of the bicontinuous electron-donor/electron-acceptor networks in active layer based on rod-coil P3HT-b-PDMAEMA block copolymers blended with CdSe QDs.

KW - CdSe Quantum Dots

KW - P3HT-b-PDMAEMA

KW - Rod-Coil Block Copolymer

KW - Solar Cells

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ER -

Hybrid nanocomposite of CdSe quantum dots and a P3HT-b-PDMAEMA block copolymer for photovoltaic applications

Abstract

Publication series

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Keywords

ASJC Scopus subject areas

UN SDGs

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