Hydrogen production from a DME reforming-membrane reactor using stainless steel-supported Knudsen membranes with high permeability

Sang Jun Park; Dong Wook Lee; Chang Yeol Yu; Kwan Young Lee; Kew Ho Lee

doi:10.1016/j.memsci.2008.02.036

Hydrogen production from a DME reforming-membrane reactor using stainless steel-supported Knudsen membranes with high permeability

Sang Jun Park, Dong Wook Lee, Chang Yeol Yu, Kwan Young Lee, Kew Ho Lee

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Stainless steel-supported composite membranes with the Knudsen-dominated permeation behavior were synthesized via the dipping-rolling-freezing-fast drying (DRFF) and soaking-rolling-freezing-fast drying (SRFF) method. A dimethyl ether (DME) steam reforming was performed in a membrane reactor using the stainless steel-supported Knudsen membrane (SKM) with remarkably high permeability. The Knudsen membrane with high permeability was used to improve DME conversion and hydrogen recovery. Compared to a conventional reactor, the DME conversion was improved up to 48% and the hydrogen recovery was 37-38% in the temperature range of 250-450 °C. Moreover, the DME steam reforming-membrane reactor was combined with water-gas shift (WGS) reaction in the permeate side of the membrane reactor to obtain high CO removal efficiency. As a result, the CO concentrations was significantly reduced to below 20 ppm in the permeate side of the membrane reactor via the WGS reaction in the temperature range of 300-450 °C.

Original language	English
Pages (from-to)	123-128
Number of pages	6
Journal	Journal of Membrane Science
Volume	318
Issue number	1-2
DOIs	https://doi.org/10.1016/j.memsci.2008.02.036
Publication status	Published - 2008 Jun 20

Keywords

DME steam reforming
Knudsen membranes
Water-gas shift reaction

ASJC Scopus subject areas

Biochemistry
General Materials Science
Physical and Theoretical Chemistry
Filtration and Separation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.memsci.2008.02.036

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title = "Hydrogen production from a DME reforming-membrane reactor using stainless steel-supported Knudsen membranes with high permeability",

abstract = "Stainless steel-supported composite membranes with the Knudsen-dominated permeation behavior were synthesized via the dipping-rolling-freezing-fast drying (DRFF) and soaking-rolling-freezing-fast drying (SRFF) method. A dimethyl ether (DME) steam reforming was performed in a membrane reactor using the stainless steel-supported Knudsen membrane (SKM) with remarkably high permeability. The Knudsen membrane with high permeability was used to improve DME conversion and hydrogen recovery. Compared to a conventional reactor, the DME conversion was improved up to 48% and the hydrogen recovery was 37-38% in the temperature range of 250-450 °C. Moreover, the DME steam reforming-membrane reactor was combined with water-gas shift (WGS) reaction in the permeate side of the membrane reactor to obtain high CO removal efficiency. As a result, the CO concentrations was significantly reduced to below 20 ppm in the permeate side of the membrane reactor via the WGS reaction in the temperature range of 300-450 °C.",

keywords = "DME steam reforming, Knudsen membranes, Water-gas shift reaction",

author = "Park, {Sang Jun} and Lee, {Dong Wook} and Yu, {Chang Yeol} and Lee, {Kwan Young} and Lee, {Kew Ho}",

year = "2008",

month = jun,

day = "20",

doi = "10.1016/j.memsci.2008.02.036",

language = "English",

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journal = "Journal of Membrane Science",

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T1 - Hydrogen production from a DME reforming-membrane reactor using stainless steel-supported Knudsen membranes with high permeability

AU - Park, Sang Jun

AU - Lee, Dong Wook

AU - Yu, Chang Yeol

AU - Lee, Kwan Young

AU - Lee, Kew Ho

PY - 2008/6/20

Y1 - 2008/6/20

N2 - Stainless steel-supported composite membranes with the Knudsen-dominated permeation behavior were synthesized via the dipping-rolling-freezing-fast drying (DRFF) and soaking-rolling-freezing-fast drying (SRFF) method. A dimethyl ether (DME) steam reforming was performed in a membrane reactor using the stainless steel-supported Knudsen membrane (SKM) with remarkably high permeability. The Knudsen membrane with high permeability was used to improve DME conversion and hydrogen recovery. Compared to a conventional reactor, the DME conversion was improved up to 48% and the hydrogen recovery was 37-38% in the temperature range of 250-450 °C. Moreover, the DME steam reforming-membrane reactor was combined with water-gas shift (WGS) reaction in the permeate side of the membrane reactor to obtain high CO removal efficiency. As a result, the CO concentrations was significantly reduced to below 20 ppm in the permeate side of the membrane reactor via the WGS reaction in the temperature range of 300-450 °C.

AB - Stainless steel-supported composite membranes with the Knudsen-dominated permeation behavior were synthesized via the dipping-rolling-freezing-fast drying (DRFF) and soaking-rolling-freezing-fast drying (SRFF) method. A dimethyl ether (DME) steam reforming was performed in a membrane reactor using the stainless steel-supported Knudsen membrane (SKM) with remarkably high permeability. The Knudsen membrane with high permeability was used to improve DME conversion and hydrogen recovery. Compared to a conventional reactor, the DME conversion was improved up to 48% and the hydrogen recovery was 37-38% in the temperature range of 250-450 °C. Moreover, the DME steam reforming-membrane reactor was combined with water-gas shift (WGS) reaction in the permeate side of the membrane reactor to obtain high CO removal efficiency. As a result, the CO concentrations was significantly reduced to below 20 ppm in the permeate side of the membrane reactor via the WGS reaction in the temperature range of 300-450 °C.

KW - DME steam reforming

KW - Knudsen membranes

KW - Water-gas shift reaction

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U2 - 10.1016/j.memsci.2008.02.036

DO - 10.1016/j.memsci.2008.02.036

M3 - Article

AN - SCOPUS:43549093967

SN - 0376-7388

VL - 318

SP - 123

EP - 128

JO - Journal of Membrane Science

JF - Journal of Membrane Science

IS - 1-2

ER -

Hydrogen production from a DME reforming-membrane reactor using stainless steel-supported Knudsen membranes with high permeability

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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