Imine-functionalized, turn-on fluorophore for DCP

Hyun Jung Kim; Seunghyun Jang; Wen Xiu Ren; Richard A. Bartsch; Honglae Sohn; Jong Seung Kim

doi:10.1016/j.snb.2010.10.028

Imine-functionalized, turn-on fluorophore for DCP

Hyun Jung Kim, Seunghyun Jang, Wen Xiu Ren, Richard A. Bartsch, Honglae Sohn, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A monopyrene-imine derivative 1 is a highly selective and sensitive "turn-on" fluorogenic probe for diethyl chlorophosphate (DCP), a stimulant for organophosphorus nerve agents. Upon addition of DCP to a solution of 1, a phosphoramidate was formed which exhibited an enhanced fluorescence emission at 425 nm. When exposed to DCP in the vapor phase, 1 impregnated on silica gel showed a sky-blue fluorescence.

Original language	English
Pages (from-to)	266-270
Number of pages	5
Journal	Sensors and Actuators, B: Chemical
Volume	153
Issue number	1
DOIs	https://doi.org/10.1016/j.snb.2010.10.028
Publication status	Published - 2011 Mar 31

Keywords

Fluorescent sensor
Nerve agent
Pyrene
Thin film image

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Instrumentation
Condensed Matter Physics
Surfaces, Coatings and Films
Metals and Alloys
Electrical and Electronic Engineering
Materials Chemistry

Access to Document

10.1016/j.snb.2010.10.028

Cite this

@article{2593fad4091d4d0fbf3a0be5341000ec,

title = "Imine-functionalized, turn-on fluorophore for DCP",

abstract = "A monopyrene-imine derivative 1 is a highly selective and sensitive {"}turn-on{"} fluorogenic probe for diethyl chlorophosphate (DCP), a stimulant for organophosphorus nerve agents. Upon addition of DCP to a solution of 1, a phosphoramidate was formed which exhibited an enhanced fluorescence emission at 425 nm. When exposed to DCP in the vapor phase, 1 impregnated on silica gel showed a sky-blue fluorescence.",

keywords = "Fluorescent sensor, Nerve agent, Pyrene, Thin film image",

author = "Kim, {Hyun Jung} and Seunghyun Jang and Ren, {Wen Xiu} and Bartsch, {Richard A.} and Honglae Sohn and Kim, {Jong Seung}",

note = "Funding Information: This research was supported by the Creative Research Initiative Program (No. 2010-0000728 ) and the National Research Foundation of Korea ( NRF-2009-351-C00032 ). ",

year = "2011",

month = mar,

day = "31",

doi = "10.1016/j.snb.2010.10.028",

language = "English",

volume = "153",

pages = "266--270",

journal = "Sensors and Actuators, B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Imine-functionalized, turn-on fluorophore for DCP

AU - Kim, Hyun Jung

AU - Jang, Seunghyun

AU - Ren, Wen Xiu

AU - Bartsch, Richard A.

AU - Sohn, Honglae

AU - Kim, Jong Seung

N1 - Funding Information: This research was supported by the Creative Research Initiative Program (No. 2010-0000728 ) and the National Research Foundation of Korea ( NRF-2009-351-C00032 ).

PY - 2011/3/31

Y1 - 2011/3/31

N2 - A monopyrene-imine derivative 1 is a highly selective and sensitive "turn-on" fluorogenic probe for diethyl chlorophosphate (DCP), a stimulant for organophosphorus nerve agents. Upon addition of DCP to a solution of 1, a phosphoramidate was formed which exhibited an enhanced fluorescence emission at 425 nm. When exposed to DCP in the vapor phase, 1 impregnated on silica gel showed a sky-blue fluorescence.

AB - A monopyrene-imine derivative 1 is a highly selective and sensitive "turn-on" fluorogenic probe for diethyl chlorophosphate (DCP), a stimulant for organophosphorus nerve agents. Upon addition of DCP to a solution of 1, a phosphoramidate was formed which exhibited an enhanced fluorescence emission at 425 nm. When exposed to DCP in the vapor phase, 1 impregnated on silica gel showed a sky-blue fluorescence.

KW - Fluorescent sensor

KW - Nerve agent

KW - Pyrene

KW - Thin film image

UR - http://www.scopus.com/inward/record.url?scp=79952487944&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2010.10.028

DO - 10.1016/j.snb.2010.10.028

M3 - Article

AN - SCOPUS:79952487944

SN - 0925-4005

VL - 153

SP - 266

EP - 270

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

IS - 1

ER -

Imine-functionalized, turn-on fluorophore for DCP

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this