Impacts of environmental conditions on the sorption of volatile organic compounds onto tire powder

Dong I. Oh, Kyongphile Nam, Jae W. Park, Jee H. Khim, Yong K. Kim, Jae Y. Kim

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A series of batch tests were performed and the impacts of environmental conditions and phase change on the sorption of volatile organic compounds (VOCs) were investigated. Benzene, trichloroethylene, tetrachloroethylene, and ethylbenzene were selected as target VOCs. Sorption of VOCs onto tire powder was well demonstrated by a linear-partitioning model. Water-tire partition coefficients of VOCs (not tested in this study) could be estimated using a logarithmic relationship between observed water-tire partition coefficients and octanol-water partition coefficients of the VOCs tested. The target VOCs did not seem to compete with other VOCs significantly when sorbed onto the tire powder for the range of concentrations tested. The influence of environmental conditions, such as pH and ionic strength also did not seem to be significant. Water-tire partition coefficients of benzene, trichloroethylene, tetrachloroethylene, and ethylbenzene decreased as the sorbent dosage increased. However, they showed stable values when the sorbent dosage was greater than 10 g/L. Air-tire partition coefficient could be extrapolated from Henry's law constants and water-tire partition coefficient of VOCs.

Original languageEnglish
Pages (from-to)157-163
Number of pages7
JournalJournal of hazardous materials
Volume153
Issue number1-2
DOIs
Publication statusPublished - 2008 May 1

Bibliographical note

Funding Information:
Financial supports were provided by grant no. R01-2005-000-10675-0 from the Basic Research Program of the Korea Science & Engineering Foundation (KOSEF) and Brain Korea 21 Project. The authors would also like to thank the Research Institute of Engineering Science, Seoul National University for their helpful assistance for invaluable technical assistance.

Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.

Keywords

  • Batch test
  • Partition coefficients
  • Sorption
  • Tire powder
  • Volatile organic compounds

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

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