Importance of varying electron-accepting moieties in regular conjugated terpolymers for use in polymer solar cells

Hyung Jong Kim; Gi Eun Park; Dae Hee Lee; Min Ju Cho; Dong Hoon Choi

doi:10.1016/j.orgel.2016.08.011

Importance of varying electron-accepting moieties in regular conjugated terpolymers for use in polymer solar cells

Hyung Jong Kim, Gi Eun Park, Dae Hee Lee, Min Ju Cho, Dong Hoon Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Three A₁-D-A₂-D regular conjugated terpolymers containing diketopyrrolopyrrole, isoindigo, or thienoisoindigo moieties were synthesized. Each terpolymer with the combination of two different acceptors and thiophene as common donor displayed strong absorption from 500 nm to the near-IR region as well as different molecular energy levels. Among three terpolymers, bulk heterojunction polymer solar cell made of the terpolymer containing diketopyrrolopyrrole, isoindigo, and thiophene moieties and phenyl-C71-butyric acid methyl ester showed the highest power conversion efficiency of 6.95% due to its appropriate internal morphology and the high open circuit voltage conferred by the relatively low-lying highest occupied molecular orbital level of the polymer.

Original language	English
Pages (from-to)	256-263
Number of pages	8
Journal	Organic Electronics
Volume	38
DOIs	https://doi.org/10.1016/j.orgel.2016.08.011
Publication status	Published - 2016 Nov 1

Keywords

Diketopyrrolopyrrole
Isoindigo
Polymer solar cells
Terpolymer
Thienoisoindigo

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Biomaterials
Chemistry(all)
Condensed Matter Physics
Materials Chemistry
Electrical and Electronic Engineering

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10.1016/j.orgel.2016.08.011

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title = "Importance of varying electron-accepting moieties in regular conjugated terpolymers for use in polymer solar cells",

abstract = "Three A1-D-A2-D regular conjugated terpolymers containing diketopyrrolopyrrole, isoindigo, or thienoisoindigo moieties were synthesized. Each terpolymer with the combination of two different acceptors and thiophene as common donor displayed strong absorption from 500 nm to the near-IR region as well as different molecular energy levels. Among three terpolymers, bulk heterojunction polymer solar cell made of the terpolymer containing diketopyrrolopyrrole, isoindigo, and thiophene moieties and phenyl-C71-butyric acid methyl ester showed the highest power conversion efficiency of 6.95% due to its appropriate internal morphology and the high open circuit voltage conferred by the relatively low-lying highest occupied molecular orbital level of the polymer.",

keywords = "Diketopyrrolopyrrole, Isoindigo, Polymer solar cells, Terpolymer, Thienoisoindigo",

author = "Kim, {Hyung Jong} and Park, {Gi Eun} and Lee, {Dae Hee} and Cho, {Min Ju} and Choi, {Dong Hoon}",

note = "Funding Information: The authors acknowledge the financial support from the National Research Foundation of Korea ( NRF2012R1A2A1A01008797 ) and from Key Research Institute Program ( NRF201000020209 ). We thank KBSI for allowing the use of their HRTEM instrument. Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = nov,

day = "1",

doi = "10.1016/j.orgel.2016.08.011",

language = "English",

volume = "38",

pages = "256--263",

journal = "Organic Electronics: physics, materials, applications",

issn = "1566-1199",

publisher = "Elsevier",

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T1 - Importance of varying electron-accepting moieties in regular conjugated terpolymers for use in polymer solar cells

AU - Kim, Hyung Jong

AU - Park, Gi Eun

AU - Lee, Dae Hee

AU - Cho, Min Ju

AU - Choi, Dong Hoon

N1 - Funding Information: The authors acknowledge the financial support from the National Research Foundation of Korea ( NRF2012R1A2A1A01008797 ) and from Key Research Institute Program ( NRF201000020209 ). We thank KBSI for allowing the use of their HRTEM instrument. Publisher Copyright: © 2016 Elsevier B.V.

PY - 2016/11/1

Y1 - 2016/11/1

N2 - Three A1-D-A2-D regular conjugated terpolymers containing diketopyrrolopyrrole, isoindigo, or thienoisoindigo moieties were synthesized. Each terpolymer with the combination of two different acceptors and thiophene as common donor displayed strong absorption from 500 nm to the near-IR region as well as different molecular energy levels. Among three terpolymers, bulk heterojunction polymer solar cell made of the terpolymer containing diketopyrrolopyrrole, isoindigo, and thiophene moieties and phenyl-C71-butyric acid methyl ester showed the highest power conversion efficiency of 6.95% due to its appropriate internal morphology and the high open circuit voltage conferred by the relatively low-lying highest occupied molecular orbital level of the polymer.

AB - Three A1-D-A2-D regular conjugated terpolymers containing diketopyrrolopyrrole, isoindigo, or thienoisoindigo moieties were synthesized. Each terpolymer with the combination of two different acceptors and thiophene as common donor displayed strong absorption from 500 nm to the near-IR region as well as different molecular energy levels. Among three terpolymers, bulk heterojunction polymer solar cell made of the terpolymer containing diketopyrrolopyrrole, isoindigo, and thiophene moieties and phenyl-C71-butyric acid methyl ester showed the highest power conversion efficiency of 6.95% due to its appropriate internal morphology and the high open circuit voltage conferred by the relatively low-lying highest occupied molecular orbital level of the polymer.

KW - Diketopyrrolopyrrole

KW - Isoindigo

KW - Polymer solar cells

KW - Terpolymer

KW - Thienoisoindigo

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U2 - 10.1016/j.orgel.2016.08.011

DO - 10.1016/j.orgel.2016.08.011

M3 - Article

AN - SCOPUS:84984843558

SN - 1566-1199

VL - 38

SP - 256

EP - 263

JO - Organic Electronics: physics, materials, applications

JF - Organic Electronics: physics, materials, applications

ER -

Importance of varying electron-accepting moieties in regular conjugated terpolymers for use in polymer solar cells

Abstract

Keywords

ASJC Scopus subject areas

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