Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol-Gel Matrix Bearing an Active Chromophore

Dong Hoon Choi; Ji Hye Park; Tae Hyung Rhee; Nakjoong Kim; Sin Doo Lee

doi:10.1021/cm970311h

Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol-Gel Matrix Bearing an Active Chromophore

Dong Hoon Choi^*
, Ji Hye Park
, Tae Hyung Rhee
, Nakjoong Kim
, Sin Doo Lee

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A second-order nonlinear optical (NLO) chromophore (disperse red 1) was reacted with (3,isocyanatopropyl)triethoxysilane to form a functionalized silicon alkoxide precursor (SGDR1). To improve the temporal stability of the second-order NLO effect, we employed a thermal cross-link between the organic side groups themselves. (3-Glycidoxypropyl)-trimethoxysilane was mixed with SGDR1 in tetrahydrofuran (SGDR1/GPTS). We compared the témporal stability of the poled samples with SGDR1 and SGDR1/GPTS. We investigated second-order NLO properties of sol-gel films by virtue of second harmonic generation (SHG) and linear electrooptic (E/O) coefficient measurements for the purpose. We achieved much improvement in the temporal stability of second-order NLO effect at high temperature with the heterogeneous films.

Original language	English
Pages (from-to)	705-709
Number of pages	5
Journal	Chemistry of Materials
Volume	10
Issue number	3
DOIs	https://doi.org/10.1021/cm970311h
Publication status	Published - 1998
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol-Gel Matrix Bearing an Active Chromophore",

abstract = "A second-order nonlinear optical (NLO) chromophore (disperse red 1) was reacted with (3,isocyanatopropyl)triethoxysilane to form a functionalized silicon alkoxide precursor (SGDR1). To improve the temporal stability of the second-order NLO effect, we employed a thermal cross-link between the organic side groups themselves. (3-Glycidoxypropyl)-trimethoxysilane was mixed with SGDR1 in tetrahydrofuran (SGDR1/GPTS). We compared the t{\'e}mporal stability of the poled samples with SGDR1 and SGDR1/GPTS. We investigated second-order NLO properties of sol-gel films by virtue of second harmonic generation (SHG) and linear electrooptic (E/O) coefficient measurements for the purpose. We achieved much improvement in the temporal stability of second-order NLO effect at high temperature with the heterogeneous films.",

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year = "1998",

doi = "10.1021/cm970311h",

language = "English",

volume = "10",

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journal = "Chemistry of Materials",

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publisher = "American Chemical Society",

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T1 - Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol-Gel Matrix Bearing an Active Chromophore

AU - Choi, Dong Hoon

AU - Park, Ji Hye

AU - Rhee, Tae Hyung

AU - Kim, Nakjoong

AU - Lee, Sin Doo

PY - 1998

Y1 - 1998

N2 - A second-order nonlinear optical (NLO) chromophore (disperse red 1) was reacted with (3,isocyanatopropyl)triethoxysilane to form a functionalized silicon alkoxide precursor (SGDR1). To improve the temporal stability of the second-order NLO effect, we employed a thermal cross-link between the organic side groups themselves. (3-Glycidoxypropyl)-trimethoxysilane was mixed with SGDR1 in tetrahydrofuran (SGDR1/GPTS). We compared the témporal stability of the poled samples with SGDR1 and SGDR1/GPTS. We investigated second-order NLO properties of sol-gel films by virtue of second harmonic generation (SHG) and linear electrooptic (E/O) coefficient measurements for the purpose. We achieved much improvement in the temporal stability of second-order NLO effect at high temperature with the heterogeneous films.

AB - A second-order nonlinear optical (NLO) chromophore (disperse red 1) was reacted with (3,isocyanatopropyl)triethoxysilane to form a functionalized silicon alkoxide precursor (SGDR1). To improve the temporal stability of the second-order NLO effect, we employed a thermal cross-link between the organic side groups themselves. (3-Glycidoxypropyl)-trimethoxysilane was mixed with SGDR1 in tetrahydrofuran (SGDR1/GPTS). We compared the témporal stability of the poled samples with SGDR1 and SGDR1/GPTS. We investigated second-order NLO properties of sol-gel films by virtue of second harmonic generation (SHG) and linear electrooptic (E/O) coefficient measurements for the purpose. We achieved much improvement in the temporal stability of second-order NLO effect at high temperature with the heterogeneous films.

UR - https://www.scopus.com/pages/publications/0000750496

U2 - 10.1021/cm970311h

DO - 10.1021/cm970311h

M3 - Article

AN - SCOPUS:0000750496

SN - 0897-4756

VL - 10

SP - 705

EP - 709

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 3

ER -

Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol-Gel Matrix Bearing an Active Chromophore

Abstract

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