Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites

Joongyeon Kim; Sun Hee Park; Byung Hee Chun; Byung Hun Jeong; Jeong Sik Han; Sung Hyun Kim

doi:10.1016/j.cattod.2011.09.020

Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites

Joongyeon Kim, Sun Hee Park, Byung Hee Chun, Byung Hun Jeong, Jeong Sik Han, Sung Hyun Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction.

Original language	English
Pages (from-to)	47-53
Number of pages	7
Journal	Catalysis Today
Volume	185
Issue number	1
DOIs	https://doi.org/10.1016/j.cattod.2011.09.020
Publication status	Published - 2012 May 20

Bibliographical note

Funding Information:
This work was supported by a Korea University Grant.

Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.

Keywords

Heat of reaction
Low-molecular-weight hydrocarbons
Methylcyclohexane
Olefins
Zeolites

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1016/j.cattod.2011.09.020

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title = "Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites",

abstract = "Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.\% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction.",

keywords = "Heat of reaction, Low-molecular-weight hydrocarbons, Methylcyclohexane, Olefins, Zeolites",

author = "Joongyeon Kim and Park, \{Sun Hee\} and Chun, \{Byung Hee\} and Jeong, \{Byung Hun\} and Han, \{Jeong Sik\} and Kim, \{Sung Hyun\}",

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AU - Kim, Joongyeon

AU - Park, Sun Hee

AU - Chun, Byung Hee

AU - Jeong, Byung Hun

AU - Han, Jeong Sik

AU - Kim, Sung Hyun

PY - 2012/5/20

Y1 - 2012/5/20

N2 - Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction.

AB - Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction.

KW - Heat of reaction

KW - Low-molecular-weight hydrocarbons

KW - Methylcyclohexane

KW - Olefins

KW - Zeolites

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Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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