Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Seung Hyun Chae; Kyung Yeon Lee; Sung Jin Kim; Suk Joong Lee; Youngmee Kim

doi:10.1016/j.inoche.2016.04.026

Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Seung Hyun Chae, Kyung Yeon Lee, Sung Jin Kim, Suk Joong Lee, Youngmee Kim

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)₂. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

Original language	English
Pages (from-to)	40-44
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	69
DOIs	https://doi.org/10.1016/j.inoche.2016.04.026
Publication status	Published - 2016 Jul 1

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

Keywords

Crystal
Molecular packing
Molecular platform
Morphology
Porphyrin

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2016.04.026

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title = "Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals",

abstract = "Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.",

keywords = "Crystal, Molecular packing, Molecular platform, Morphology, Porphyrin",

author = "Chae, {Seung Hyun} and Lee, {Kyung Yeon} and Kim, {Sung Jin} and Lee, {Suk Joong} and Youngmee Kim",

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doi = "10.1016/j.inoche.2016.04.026",

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T1 - Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

AU - Chae, Seung Hyun

AU - Lee, Kyung Yeon

AU - Kim, Sung Jin

AU - Lee, Suk Joong

AU - Kim, Youngmee

PY - 2016/7/1

Y1 - 2016/7/1

N2 - Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

AB - Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

KW - Crystal

KW - Molecular packing

KW - Molecular platform

KW - Morphology

KW - Porphyrin

UR - http://www.scopus.com/inward/record.url?scp=84965108921&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.04.026

DO - 10.1016/j.inoche.2016.04.026

M3 - Article

AN - SCOPUS:84965108921

SN - 1387-7003

VL - 69

SP - 40

EP - 44

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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