Interaction of NO with the MgO(100) surface studied by infrared reflection absorption spectroscopy

C. M. Kim, C. W. Yi, B. K. Min, A. K. Santra, D. W. Goodman

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    18 Citations (Scopus)

    Abstract

    Infrared reflection absorption spectroscopy (IRAS) at low temperatures (ca. 40 K) has been used to study the interaction of NO with highly ordered MgO(100) thin films. Dimer formation has been observed in the multilayer regime at (<60 K) and in the monolayer regime at 60-70 K. Using 15NO, it is shown that dimeric NO, (NO)2, is the key intermediate in the formation of N2O above 70 K.

    Original languageEnglish
    Pages (from-to)5651-5652
    Number of pages2
    JournalLangmuir
    Volume18
    Issue number15
    DOIs
    Publication statusPublished - 2002 Jul 23

    Bibliographical note

    Funding Information:
    * Research supported by National Research Council of Italy, Special Project RAISA, Sub-project N. 1 Paper N. 1412

    ASJC Scopus subject areas

    • General Materials Science
    • Condensed Matter Physics
    • Surfaces and Interfaces
    • Spectroscopy
    • Electrochemistry

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