Intermodular contact-tuned magnetic nature in one-dimensional 3d-5d bimetallic systems: From a metamagnet to a single-chain magnet

Woo Choi Seok; Young Kwak Hyun; Hee Yoon Jung; Chan Kim Hyoung; Kwan Koh Eui; Seop Hong Chang

doi:10.1021/ic801699p

Intermodular contact-tuned magnetic nature in one-dimensional 3d-5d bimetallic systems: From a metamagnet to a single-chain magnet

Woo Choi Seok, Young Kwak Hyun, Hee Yoon Jung, Chan Kim Hyoung, Kwan Koh Eui, Seop Hong Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Assembling [W(CN)₆(bpy)]^- and magnetic anisotropic Mn Schiff bases produced two Mn^III(3d)-W^V(5d) bimetallic chains. Modulation of the types and degrees of interchain π-π interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.

Original language	English
Pages (from-to)	10214-10216
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	22
DOIs	https://doi.org/10.1021/ic801699p
Publication status	Published - 2008 Nov 17

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic801699p

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abstract = "Assembling [W(CN)6(bpy)]- and magnetic anisotropic Mn Schiff bases produced two MnIII(3d)-WV(5d) bimetallic chains. Modulation of the types and degrees of interchain π-π interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.",

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AU - Hyun, Young Kwak

AU - Jung, Hee Yoon

AU - Hyoung, Chan Kim

AU - Eui, Kwan Koh

AU - Chang, Seop Hong

PY - 2008/11/17

Y1 - 2008/11/17

N2 - Assembling [W(CN)6(bpy)]- and magnetic anisotropic Mn Schiff bases produced two MnIII(3d)-WV(5d) bimetallic chains. Modulation of the types and degrees of interchain π-π interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.

AB - Assembling [W(CN)6(bpy)]- and magnetic anisotropic Mn Schiff bases produced two MnIII(3d)-WV(5d) bimetallic chains. Modulation of the types and degrees of interchain π-π interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.

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Intermodular contact-tuned magnetic nature in one-dimensional 3d-5d bimetallic systems: From a metamagnet to a single-chain magnet

Abstract

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