Ion-selective nanoplasmonic optical sensor

Taewook Kang; Yeonho Choi; Dukhyun Choi; Eunice Lee; Luke P. Lee

Ion-selective nanoplasmonic optical sensor

Taewook Kang
, Yeonho Choi
, Dukhyun Choi
, Eunice Lee
, Luke P. Lee

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

In this paper, we demonstrate a label-free ion-selective optical sensor for metal ion. This sensing mechanism is based on (1) selective formation of metal-ligand complex on the surface of nanoplasmonic probes and (2) selective plasmonic resonance energy transfer (PRET) between conjugated metal-ligand complex and gold nanoplasmonic probes (GNPs). We used functionalized GNP with ethylenediamine ligands in order to demonstrate high selectivity and sensitivity toward Cu²⁺. Due to the selective energy transfer from GNP to dd transition of the Cu²⁺ complex, the scattering spectrum of GNP changes quantitatively down to 1 nM of Cu²⁺. Moreover, this Cu²⁺ nanoplasmonic senor has selectivity over Na⁺, Ca²⁺, K⁺, and Mg²⁺

Original language	English
Title of host publication	Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007
Editors	Jean-Louis Viovy, Patrick Tabeling, Stephanie Descroix, Laurent Malaquin
Publisher	Chemical and Biological Microsystems Society
Pages	464-466
Number of pages	3
ISBN (Electronic)	9780979806407
Publication status	Published - 2007
Externally published	Yes
Event	11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007 - Paris, France Duration: 2007 Oct 7 → 2007 Oct 11

Publication series

Name	Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007

Conference

Conference	11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007
Country/Territory	France
City	Paris
Period	07/10/7 → 07/10/11

Bibliographical note

Funding Information:
This work was supported by a grant (code #: 05K1501-02810) from ‘Center for Nanostructured Materials Technology’ under ‘21st Century Frontier R&D Programs’ of the Ministry of Science and Technology, Korea.

Publisher Copyright:
© 2007 CBMS.

Keywords

Gold Nanoparticle
Metal-Ligand Complex
Plasmonic Resonance Energy Transfer
Rayleigh Scattering

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Bioengineering

Cite this

Kang, T., Choi, Y., Choi, D., Lee, E., & Lee, L. P. (2007). Ion-selective nanoplasmonic optical sensor. In J.-L. Viovy, P. Tabeling, S. Descroix, & L. Malaquin (Eds.), Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007 (pp. 464-466). (Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007). Chemical and Biological Microsystems Society.

Ion-selective nanoplasmonic optical sensor. / Kang, Taewook; Choi, Yeonho; Choi, Dukhyun et al.
Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. ed. / Jean-Louis Viovy; Patrick Tabeling; Stephanie Descroix; Laurent Malaquin. Chemical and Biological Microsystems Society, 2007. p. 464-466 (Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Kang, T, Choi, Y, Choi, D, Lee, E & Lee, LP 2007, Ion-selective nanoplasmonic optical sensor. in J-L Viovy, P Tabeling, S Descroix & L Malaquin (eds), Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007, Chemical and Biological Microsystems Society, pp. 464-466, 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007, Paris, France, 07/10/7.

Kang T, Choi Y, Choi D, Lee E, Lee LP. Ion-selective nanoplasmonic optical sensor. In Viovy JL, Tabeling P, Descroix S, Malaquin L, editors, Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. Chemical and Biological Microsystems Society. 2007. p. 464-466. (Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007).

Kang, Taewook ; Choi, Yeonho ; Choi, Dukhyun et al. / Ion-selective nanoplasmonic optical sensor. Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. editor / Jean-Louis Viovy ; Patrick Tabeling ; Stephanie Descroix ; Laurent Malaquin. Chemical and Biological Microsystems Society, 2007. pp. 464-466 (Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007).

@inproceedings{c094c67f9fbb4571b0e1ca9d7bd3fcd1,

title = "Ion-selective nanoplasmonic optical sensor",

abstract = "In this paper, we demonstrate a label-free ion-selective optical sensor for metal ion. This sensing mechanism is based on (1) selective formation of metal-ligand complex on the surface of nanoplasmonic probes and (2) selective plasmonic resonance energy transfer (PRET) between conjugated metal-ligand complex and gold nanoplasmonic probes (GNPs). We used functionalized GNP with ethylenediamine ligands in order to demonstrate high selectivity and sensitivity toward Cu2+. Due to the selective energy transfer from GNP to dd transition of the Cu2+ complex, the scattering spectrum of GNP changes quantitatively down to 1 nM of Cu2+. Moreover, this Cu2+ nanoplasmonic senor has selectivity over Na+, Ca2+, K+, and Mg2+",

keywords = "Gold Nanoparticle, Metal-Ligand Complex, Plasmonic Resonance Energy Transfer, Rayleigh Scattering",

author = "Taewook Kang and Yeonho Choi and Dukhyun Choi and Eunice Lee and Lee, \{Luke P.\}",

note = "Funding Information: This work was supported by a grant (code \#: 05K1501-02810) from {\textquoteleft}Center for Nanostructured Materials Technology{\textquoteright} under {\textquoteleft}21st Century Frontier R\&D Programs{\textquoteright} of the Ministry of Science and Technology, Korea. Publisher Copyright: {\textcopyright} 2007 CBMS.; 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007 ; Conference date: 07-10-2007 Through 11-10-2007",

year = "2007",

language = "English",

series = "Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007",

publisher = "Chemical and Biological Microsystems Society",

pages = "464--466",

editor = "Jean-Louis Viovy and Patrick Tabeling and Stephanie Descroix and Laurent Malaquin",

booktitle = "Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007",

}

TY - GEN

T1 - Ion-selective nanoplasmonic optical sensor

AU - Kang, Taewook

AU - Choi, Yeonho

AU - Choi, Dukhyun

AU - Lee, Eunice

AU - Lee, Luke P.

N1 - Funding Information: This work was supported by a grant (code #: 05K1501-02810) from ‘Center for Nanostructured Materials Technology’ under ‘21st Century Frontier R&D Programs’ of the Ministry of Science and Technology, Korea. Publisher Copyright: © 2007 CBMS.

PY - 2007

Y1 - 2007

N2 - In this paper, we demonstrate a label-free ion-selective optical sensor for metal ion. This sensing mechanism is based on (1) selective formation of metal-ligand complex on the surface of nanoplasmonic probes and (2) selective plasmonic resonance energy transfer (PRET) between conjugated metal-ligand complex and gold nanoplasmonic probes (GNPs). We used functionalized GNP with ethylenediamine ligands in order to demonstrate high selectivity and sensitivity toward Cu2+. Due to the selective energy transfer from GNP to dd transition of the Cu2+ complex, the scattering spectrum of GNP changes quantitatively down to 1 nM of Cu2+. Moreover, this Cu2+ nanoplasmonic senor has selectivity over Na+, Ca2+, K+, and Mg2+

AB - In this paper, we demonstrate a label-free ion-selective optical sensor for metal ion. This sensing mechanism is based on (1) selective formation of metal-ligand complex on the surface of nanoplasmonic probes and (2) selective plasmonic resonance energy transfer (PRET) between conjugated metal-ligand complex and gold nanoplasmonic probes (GNPs). We used functionalized GNP with ethylenediamine ligands in order to demonstrate high selectivity and sensitivity toward Cu2+. Due to the selective energy transfer from GNP to dd transition of the Cu2+ complex, the scattering spectrum of GNP changes quantitatively down to 1 nM of Cu2+. Moreover, this Cu2+ nanoplasmonic senor has selectivity over Na+, Ca2+, K+, and Mg2+

KW - Gold Nanoparticle

KW - Metal-Ligand Complex

KW - Plasmonic Resonance Energy Transfer

KW - Rayleigh Scattering

UR - https://www.scopus.com/pages/publications/85088677932

M3 - Conference contribution

AN - SCOPUS:85088677932

T3 - Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007

SP - 464

EP - 466

BT - Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007

A2 - Viovy, Jean-Louis

A2 - Tabeling, Patrick

A2 - Descroix, Stephanie

A2 - Malaquin, Laurent

PB - Chemical and Biological Microsystems Society

T2 - 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007

Y2 - 7 October 2007 through 11 October 2007

ER -

Ion-selective nanoplasmonic optical sensor

Abstract

Publication series

Conference

Bibliographical note

Keywords

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this