Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: Strategic realization of ultra-accelerated nanocatalysis

Kie Yong Cho; Yong Sik Yeom; Heun Young Seo; Pradip Kumar; Albert S. Lee; Kyung Youl Baek; Ho Gyu Yoon

doi:10.1039/c5ta06076a

Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: Strategic realization of ultra-accelerated nanocatalysis

Kie Yong Cho
, Yong Sik Yeom
, Heun Young Seo
, Pradip Kumar
, Albert S. Lee
, Kyung Youl Baek
, Ho Gyu Yoon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

We synthesized an ultra-fine Pd nanocatalyst supported by ionic block copolymer doped reduced graphene oxide (Pd-PIBrGO) for ultra-accelerated nanocatalysis. This hybrid catalyst exhibited exceptionally advanced catalytic performance for the reduction of methylene blue using miniscule quantities of Pd-PIBrGO due to facilitated diffusion of reagents, resulting in full reduction within a few seconds and showing a 280-fold increase of the rate constant over Pd-rGO without ionic block copolymers.

Original language	English
Pages (from-to)	20471-20476
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	3
Issue number	41
DOIs	https://doi.org/10.1039/c5ta06076a
Publication status	Published - 2015

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

ASJC Scopus subject areas

General Chemistry
Renewable Energy, Sustainability and the Environment
General Materials Science

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1039/c5ta06076a

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title = "Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: Strategic realization of ultra-accelerated nanocatalysis",

abstract = "We synthesized an ultra-fine Pd nanocatalyst supported by ionic block copolymer doped reduced graphene oxide (Pd-PIBrGO) for ultra-accelerated nanocatalysis. This hybrid catalyst exhibited exceptionally advanced catalytic performance for the reduction of methylene blue using miniscule quantities of Pd-PIBrGO due to facilitated diffusion of reagents, resulting in full reduction within a few seconds and showing a 280-fold increase of the rate constant over Pd-rGO without ionic block copolymers.",

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doi = "10.1039/c5ta06076a",

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T2 - Strategic realization of ultra-accelerated nanocatalysis

AU - Cho, Kie Yong

AU - Yeom, Yong Sik

AU - Seo, Heun Young

AU - Kumar, Pradip

AU - Lee, Albert S.

AU - Baek, Kyung Youl

AU - Yoon, Ho Gyu

PY - 2015

Y1 - 2015

N2 - We synthesized an ultra-fine Pd nanocatalyst supported by ionic block copolymer doped reduced graphene oxide (Pd-PIBrGO) for ultra-accelerated nanocatalysis. This hybrid catalyst exhibited exceptionally advanced catalytic performance for the reduction of methylene blue using miniscule quantities of Pd-PIBrGO due to facilitated diffusion of reagents, resulting in full reduction within a few seconds and showing a 280-fold increase of the rate constant over Pd-rGO without ionic block copolymers.

AB - We synthesized an ultra-fine Pd nanocatalyst supported by ionic block copolymer doped reduced graphene oxide (Pd-PIBrGO) for ultra-accelerated nanocatalysis. This hybrid catalyst exhibited exceptionally advanced catalytic performance for the reduction of methylene blue using miniscule quantities of Pd-PIBrGO due to facilitated diffusion of reagents, resulting in full reduction within a few seconds and showing a 280-fold increase of the rate constant over Pd-rGO without ionic block copolymers.

UR - https://www.scopus.com/pages/publications/84944186742

U2 - 10.1039/c5ta06076a

DO - 10.1039/c5ta06076a

M3 - Article

AN - SCOPUS:84944186742

SN - 2050-7488

VL - 3

SP - 20471

EP - 20476

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 41

ER -

Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: Strategic realization of ultra-accelerated nanocatalysis

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

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