Ionic liquids as benign catalysts for the carbonylation of amines to formamides

Young Seop Choi; Yu Na Shim; Jeesun Lee; Jung Hee Yoon; Chang Seop Hong; Minserk Cheong; Hoon Sik Kim; Ho Gyeom Jang; Je Seung Lee

doi:10.1016/j.apcata.2011.07.016

Ionic liquids as benign catalysts for the carbonylation of amines to formamides

Young Seop Choi, Yu Na Shim, Jeesun Lee, Jung Hee Yoon, Chang Seop Hong, Minserk Cheong, Hoon Sik Kim, Ho Gyeom Jang, Je Seung Lee

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO₃]), prepared from the reaction of [BMIm]Cl with K₂CO₃ in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO₃] could be ascribed to the bi-functional actions of [HCO₃]^- as a hydrogen atom acceptor and a donor.

Original language	English
Pages (from-to)	87-92
Number of pages	6
Journal	Applied Catalysis A: General
Volume	404
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2011.07.016
Publication status	Published - 2011 Sept 19

Bibliographical note

Funding Information:
The authors acknowledge the financial support by grants (AC3-101) from Carbon Dioxide Reduction & Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of Korean government.

Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.

Keywords

Amines
Carbonylation
Formamides
Hydrogen carbonate
Ionic liquids

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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10.1016/j.apcata.2011.07.016

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title = "Ionic liquids as benign catalysts for the carbonylation of amines to formamides",

abstract = "1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3]- as a hydrogen atom acceptor and a donor.",

keywords = "Amines, Carbonylation, Formamides, Hydrogen carbonate, Ionic liquids",

author = "Choi, {Young Seop} and Shim, {Yu Na} and Jeesun Lee and Yoon, {Jung Hee} and Hong, {Chang Seop} and Minserk Cheong and Kim, {Hoon Sik} and Jang, {Ho Gyeom} and Lee, {Je Seung}",

note = "Funding Information: The authors acknowledge the financial support by grants (AC3-101) from Carbon Dioxide Reduction & Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of Korean government. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.",

year = "2011",

month = sep,

day = "19",

doi = "10.1016/j.apcata.2011.07.016",

language = "English",

volume = "404",

pages = "87--92",

journal = "Applied Catalysis A: General",

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AU - Choi, Young Seop

AU - Shim, Yu Na

AU - Lee, Jeesun

AU - Yoon, Jung Hee

AU - Hong, Chang Seop

AU - Cheong, Minserk

AU - Kim, Hoon Sik

AU - Jang, Ho Gyeom

AU - Lee, Je Seung

N1 - Funding Information: The authors acknowledge the financial support by grants (AC3-101) from Carbon Dioxide Reduction & Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of Korean government. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.

PY - 2011/9/19

Y1 - 2011/9/19

N2 - 1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3]- as a hydrogen atom acceptor and a donor.

AB - 1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3]- as a hydrogen atom acceptor and a donor.

KW - Amines

KW - Carbonylation

KW - Formamides

KW - Hydrogen carbonate

KW - Ionic liquids

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ER -

Ionic liquids as benign catalysts for the carbonylation of amines to formamides

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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