Janus Graphene Oxide Sheets with Fe3O4Nanoparticles and Polydopamine as Anodes for Lithium-Ion Batteries

Jiwon Jang, Seok Hyun Song, Hyeri Kim, Junsoo Moon, Hyungju Ahn, Kyoung Il Jo, Joona Bang, Hyungsub Kim, Jaseung Koo

Research output: Contribution to journalArticlepeer-review

36 Citations (Scopus)

Abstract

In this study, a one-step process to fabricate "Janus"-structured nanocomposites with iron oxide (Fe3O4) nanoparticles (Fe3O4 NPs) and polydopamine (PDA) on each side of a graphene oxide (GO) nanosheet using the Langmuir-Schaefer technique has been proposed. The Fe3O4 NPs-GO hybrid is used as a high-capacity active material, while PDA is added as a binder due to its unique wet-resistant adhesive property. The transmission electron microscopy image shows a superlattice-like out-of-plane section of the multilayered nanocomposite, which maximizes the density of the composite materials. Grazing-incidence small-angle X-ray scattering results combined with scanning electron microscopy images confirm that the multilayered Janus composite exhibits an in-plane hexagonal array structure of closely packed Fe3O4 NPs. This Janus multilayered structure is expected to maximize the amount of active material in a specific volume and reduce volume changes caused by the conversion reaction of Fe3O4 NPs. According to the electrochemical results, the Janus multilayer electrode delivers an excellent capacity of ∼903 mAh g-1 at a current density of 200 mA g-1 and a reversible capacity of ∼639 mAh g-1 at 1 A g-1 up to the 1800th cycle, indicating that this Janus composite can be a promising anode for Li-ion batteries.

Original languageEnglish
Pages (from-to)14786-14795
Number of pages10
JournalACS Applied Materials and Interfaces
Volume13
Issue number12
DOIs
Publication statusPublished - 2021 Mar 31

Bibliographical note

Funding Information:
This work was supported by a grant from the National Research Foundation of Korea under Contract No. 2019R1F1A1059109 and the Korea Institute for Advancement of Technology funded by the government (Ministry of Trade, Industry, and Energy) under Contract P0012770 (professional human resources training project).

Publisher Copyright:
© 2021 American Chemical Society.

Keywords

  • 2D Janus material
  • Langmuir-Schaefer technique
  • anode
  • graphene oxide
  • iron oxide nanoparticle
  • lithium-ion batteries
  • polydopamine

ASJC Scopus subject areas

  • General Materials Science

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