Large-Scale Synthesis of Uniform PbI2(DMSO) Complex Powder by Solvent Extraction Method for Efficient Metal Halide Perovskite Solar Cells

Sang Jin Lee; Jin Hyuck Heo; Sang Hyuk Im

doi:10.1021/acsami.9b20493

Large-Scale Synthesis of Uniform PbI₂(DMSO) Complex Powder by Solvent Extraction Method for Efficient Metal Halide Perovskite Solar Cells

Sang Jin Lee, Jin Hyuck Heo, Sang Hyuk Im

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

PbI₂(DMSO) complex powder, which is essential to fabricate efficient metal halide perovskite solar cells (MHP SCs), was synthesized by liquid phase solvent extraction process irrespective of reaction volume scale. The isopropanol (IPA) solvent could selectively extract the DMSO from PbI₂(DMSO)₂ powder during extraction process so that compositionally uniform PbI₂(DMSO) powder could be obtained in a large scale process, whereas the vacuum drying process could not produce uniform PbI₂(DMSO) powder. Due to the compositional uniformity of PbI₂(DMSO) powders prepared by solvent extraction process, the MHP SCs could be fabricated very reproducibly.

Original language	English
Pages (from-to)	8233-8239
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	12
Issue number	7
DOIs	https://doi.org/10.1021/acsami.9b20493
Publication status	Published - 2020 Feb 19

Bibliographical note

Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT & Future Planning (Basic Science Research Program (No. 2014R1A5A1009799)), and the Technology Development Program to Solve Climate Change (No. 2015M1A2A2055631) and the Ministry of Trade, Industry & Energy, Republic of Korea (New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (No. 20163010012470)).

Publisher Copyright:
Copyright © 2020 American Chemical Society.

Keywords

PbI(DMSO) powder
metal halide perovskite
scale-up
solar cells
solvent extraction

ASJC Scopus subject areas

General Materials Science

Access to Document

10.1021/acsami.9b20493

Cite this

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title = "Large-Scale Synthesis of Uniform PbI2(DMSO) Complex Powder by Solvent Extraction Method for Efficient Metal Halide Perovskite Solar Cells",

abstract = "PbI2(DMSO) complex powder, which is essential to fabricate efficient metal halide perovskite solar cells (MHP SCs), was synthesized by liquid phase solvent extraction process irrespective of reaction volume scale. The isopropanol (IPA) solvent could selectively extract the DMSO from PbI2(DMSO)2 powder during extraction process so that compositionally uniform PbI2(DMSO) powder could be obtained in a large scale process, whereas the vacuum drying process could not produce uniform PbI2(DMSO) powder. Due to the compositional uniformity of PbI2(DMSO) powders prepared by solvent extraction process, the MHP SCs could be fabricated very reproducibly.",

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author = "Lee, {Sang Jin} and Heo, {Jin Hyuck} and Im, {Sang Hyuk}",

note = "Funding Information: This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT & Future Planning (Basic Science Research Program (No. 2014R1A5A1009799)), and the Technology Development Program to Solve Climate Change (No. 2015M1A2A2055631) and the Ministry of Trade, Industry & Energy, Republic of Korea (New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (No. 20163010012470)). Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

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AU - Heo, Jin Hyuck

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N1 - Funding Information: This study was supported by the National Research Foundation of Korea (NRF) under the Ministry of Science, ICT & Future Planning (Basic Science Research Program (No. 2014R1A5A1009799)), and the Technology Development Program to Solve Climate Change (No. 2015M1A2A2055631) and the Ministry of Trade, Industry & Energy, Republic of Korea (New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (No. 20163010012470)). Publisher Copyright: Copyright © 2020 American Chemical Society.

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N2 - PbI2(DMSO) complex powder, which is essential to fabricate efficient metal halide perovskite solar cells (MHP SCs), was synthesized by liquid phase solvent extraction process irrespective of reaction volume scale. The isopropanol (IPA) solvent could selectively extract the DMSO from PbI2(DMSO)2 powder during extraction process so that compositionally uniform PbI2(DMSO) powder could be obtained in a large scale process, whereas the vacuum drying process could not produce uniform PbI2(DMSO) powder. Due to the compositional uniformity of PbI2(DMSO) powders prepared by solvent extraction process, the MHP SCs could be fabricated very reproducibly.

AB - PbI2(DMSO) complex powder, which is essential to fabricate efficient metal halide perovskite solar cells (MHP SCs), was synthesized by liquid phase solvent extraction process irrespective of reaction volume scale. The isopropanol (IPA) solvent could selectively extract the DMSO from PbI2(DMSO)2 powder during extraction process so that compositionally uniform PbI2(DMSO) powder could be obtained in a large scale process, whereas the vacuum drying process could not produce uniform PbI2(DMSO) powder. Due to the compositional uniformity of PbI2(DMSO) powders prepared by solvent extraction process, the MHP SCs could be fabricated very reproducibly.

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