Li-ion conductivity in Li2O-B2O3-V 2O5 glass system

Young Il Lee; Jong Heun Lee; Seong Hyeon Hong; Youngsin Park

doi:10.1016/j.ssi.2004.08.024

Li-ion conductivity in Li₂O-B₂O₃-V ₂O₅ glass system

Young Il Lee, Jong Heun Lee, Seong Hyeon Hong, Youngsin Park

Research output: Contribution to journal › Conference article › peer-review

48 Citations (Scopus)

Abstract

A new composition for Li⁺ conducting glass with an ionic conductivity >10^-6S/cm was suggested in Li₂O-B ₂O₃-V₂O₅ system. The maximum conductivity was found along the composition lines yLi₂O-(95-y)B ₂O₃-5V₂O₅ (45≤y≤47) and zLi₂O-50B₂O₃-(50-z)V₂O₅ (45≤z≤48). The conductivity of the binary Li₂O-B ₂O₃ glasses with an identical Li₂O content is significantly smaller than that of the ternary Li₂O-B ₂O₃-V₂O₅ glasses, which indicated a mixed former effect between B₂O₃ and V₂O ₅. The improvement in ionic conduction was discussed in relation to the change in the glass structure.

Original language	English
Pages (from-to)	687-690
Number of pages	4
Journal	Solid State Ionics
Volume	175
Issue number	1-4
DOIs	https://doi.org/10.1016/j.ssi.2004.08.024
Publication status	Published - 2004 Nov 30
Externally published	Yes
Event	Fourteenth International Conference on Solid State Ionics - Monterey, CA., United States Duration: 2003 Jun 22 → 2003 Jun 27

Keywords

Impedance spectroscopy
LiO-BO-v O glass
Lithium ion conductivity
Thin-film battery

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/j.ssi.2004.08.024

Cite this

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title = "Li-ion conductivity in Li2O-B2O3-V 2O5 glass system",

abstract = "A new composition for Li+ conducting glass with an ionic conductivity >10-6S/cm was suggested in Li2O-B 2O3-V2O5 system. The maximum conductivity was found along the composition lines yLi2O-(95-y)B 2O3-5V2O5 (45≤y≤47) and zLi2O-50B2O3-(50-z)V2O5 (45≤z≤48). The conductivity of the binary Li2O-B 2O3 glasses with an identical Li2O content is significantly smaller than that of the ternary Li2O-B 2O3-V2O5 glasses, which indicated a mixed former effect between B2O3 and V2O 5. The improvement in ionic conduction was discussed in relation to the change in the glass structure.",

keywords = "Impedance spectroscopy, LiO-BO-v O glass, Lithium ion conductivity, Thin-film battery",

author = "Lee, {Young Il} and Lee, {Jong Heun} and Hong, {Seong Hyeon} and Youngsin Park",

year = "2004",

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doi = "10.1016/j.ssi.2004.08.024",

language = "English",

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journal = "Solid State Ionics",

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TY - JOUR

T1 - Li-ion conductivity in Li2O-B2O3-V 2O5 glass system

AU - Lee, Young Il

AU - Lee, Jong Heun

AU - Hong, Seong Hyeon

AU - Park, Youngsin

PY - 2004/11/30

Y1 - 2004/11/30

N2 - A new composition for Li+ conducting glass with an ionic conductivity >10-6S/cm was suggested in Li2O-B 2O3-V2O5 system. The maximum conductivity was found along the composition lines yLi2O-(95-y)B 2O3-5V2O5 (45≤y≤47) and zLi2O-50B2O3-(50-z)V2O5 (45≤z≤48). The conductivity of the binary Li2O-B 2O3 glasses with an identical Li2O content is significantly smaller than that of the ternary Li2O-B 2O3-V2O5 glasses, which indicated a mixed former effect between B2O3 and V2O 5. The improvement in ionic conduction was discussed in relation to the change in the glass structure.

AB - A new composition for Li+ conducting glass with an ionic conductivity >10-6S/cm was suggested in Li2O-B 2O3-V2O5 system. The maximum conductivity was found along the composition lines yLi2O-(95-y)B 2O3-5V2O5 (45≤y≤47) and zLi2O-50B2O3-(50-z)V2O5 (45≤z≤48). The conductivity of the binary Li2O-B 2O3 glasses with an identical Li2O content is significantly smaller than that of the ternary Li2O-B 2O3-V2O5 glasses, which indicated a mixed former effect between B2O3 and V2O 5. The improvement in ionic conduction was discussed in relation to the change in the glass structure.

KW - Impedance spectroscopy

KW - LiO-BO-v O glass

KW - Lithium ion conductivity

KW - Thin-film battery

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JF - Solid State Ionics

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T2 - Fourteenth International Conference on Solid State Ionics

Y2 - 22 June 2003 through 27 June 2003

ER -