Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K

Tae Gyu Lee; Sang Young Lim; Kwang Ho Song; Jaehoon Choe

doi:10.1021/je401056v

Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K

Tae Gyu Lee, Sang Young Lim, Kwang Ho Song, Jaehoon Choe

Department of Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The phase behavior of a temperature-dependent multicomponent system was investigated for ternary systems comprising a polar aprotic solvent, a solubility mediator, and aliphatic hydrocarbons such as octane, decane, or dodecane. The experimental tie-line composition and binodal composition were obtained for the ternary system of 4-methyl-1,3-dioxolan-2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary system of acetonitrile + morpholine + octane, decane, or dodecane at two different temperatures, 298.15 K and 313.15 K. The distribution ratios of 1,4-dimethylbenzene and morpholine were determined, and the experimental tie-line results were adequately correlated using the nonrandom two-liquid (NRTL) activity coefficient model by utilizing the obtained binary interaction parameter.

Original language	English
Pages (from-to)	890-895
Number of pages	6
Journal	Journal of Chemical and Engineering Data
Volume	59
Issue number	3
DOIs	https://doi.org/10.1021/je401056v
Publication status	Published - 2014 Mar 13

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Chemistry(all)
Chemical Engineering(all)

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Lee, T. G., Lim, S. Y., Song, K. H., & Choe, J. (2014). Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K. Journal of Chemical and Engineering Data, 59(3), 890-895. https://doi.org/10.1021/je401056v

Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K. / Lee, Tae Gyu; Lim, Sang Young; Song, Kwang Ho et al.
In: Journal of Chemical and Engineering Data, Vol. 59, No. 3, 13.03.2014, p. 890-895.

Research output: Contribution to journal › Article › peer-review

Lee, TG, Lim, SY, Song, KH & Choe, J 2014, 'Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K', Journal of Chemical and Engineering Data, vol. 59, no. 3, pp. 890-895. https://doi.org/10.1021/je401056v

Lee, Tae Gyu ; Lim, Sang Young ; Song, Kwang Ho et al. / Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K. In: Journal of Chemical and Engineering Data. 2014 ; Vol. 59, No. 3. pp. 890-895.

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title = "Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K",

abstract = "The phase behavior of a temperature-dependent multicomponent system was investigated for ternary systems comprising a polar aprotic solvent, a solubility mediator, and aliphatic hydrocarbons such as octane, decane, or dodecane. The experimental tie-line composition and binodal composition were obtained for the ternary system of 4-methyl-1,3-dioxolan-2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary system of acetonitrile + morpholine + octane, decane, or dodecane at two different temperatures, 298.15 K and 313.15 K. The distribution ratios of 1,4-dimethylbenzene and morpholine were determined, and the experimental tie-line results were adequately correlated using the nonrandom two-liquid (NRTL) activity coefficient model by utilizing the obtained binary interaction parameter.",

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Liquid-liquid equilibria for the ternary systems of 4-methyl-1,3-dioxolan- 2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary systems of acetonitrile + morpholine + octane, decane, or dodecane at 313.15 K or 298.15 K

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