Low-temperature oxidative coupling of methane using alkaline earth metal oxide-supported perovskites

Seoyeon Lim; Jae Wook Choi; Dong Jin Suh; Ung Lee; Kwang Ho Song; Jeong Myeong Ha

doi:10.1016/j.cattod.2019.11.014

Low-temperature oxidative coupling of methane using alkaline earth metal oxide-supported perovskites

Seoyeon Lim, Jae Wook Choi, Dong Jin Suh, Ung Lee, Kwang Ho Song, Jeong Myeong Ha

Department of Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Perovskite-supported alkaline-earth metal oxide catalysts were prepared for application in the oxidative coupling of methane (OCM). The selective production of C₂₊ compounds, including ethane, ethylene, acetylene, propane, and propylene, was observed at reaction temperatures < 700 °C. This lower reaction temperature was not achieved with pure perovskites but only with the combination of alkaline-earth metal oxides and perovskite supports. The formation of complex mixed oxides, such as Ba-Ca-Ti-O_x, Ba-Sr-Ti-O_x, and Ba₂TiO₄, was also observed for these catalysts. This contributed to the improved C₂₊ yield at the lower reaction temperature. The strong basicity, which contributes to the improved OCM activity, was also observed for these catalysts.

Original language	English
Pages (from-to)	127-133
Number of pages	7
Journal	Catalysis Today
Volume	352
DOIs	https://doi.org/10.1016/j.cattod.2019.11.014
Publication status	Published - 2020 Aug 1

Keywords

Alkaline-earth metal oxide
Barium oxide
Low temperature
Methane
Oxidative coupling
Perovskite

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1016/j.cattod.2019.11.014

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title = "Low-temperature oxidative coupling of methane using alkaline earth metal oxide-supported perovskites",

abstract = "Perovskite-supported alkaline-earth metal oxide catalysts were prepared for application in the oxidative coupling of methane (OCM). The selective production of C2+ compounds, including ethane, ethylene, acetylene, propane, and propylene, was observed at reaction temperatures < 700 °C. This lower reaction temperature was not achieved with pure perovskites but only with the combination of alkaline-earth metal oxides and perovskite supports. The formation of complex mixed oxides, such as Ba-Ca-Ti-Ox, Ba-Sr-Ti-Ox, and Ba2TiO4, was also observed for these catalysts. This contributed to the improved C2+ yield at the lower reaction temperature. The strong basicity, which contributes to the improved OCM activity, was also observed for these catalysts.",

keywords = "Alkaline-earth metal oxide, Barium oxide, Low temperature, Methane, Oxidative coupling, Perovskite",

author = "Seoyeon Lim and Choi, {Jae Wook} and {Jin Suh}, Dong and Ung Lee and Song, {Kwang Ho} and Ha, {Jeong Myeong}",

note = "Funding Information: This work was supported by C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT . ( 2015M3D3A1A01064900 ). Appendix A Funding Information: This work was supported by C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT. (2015M3D3A1A01064900). Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2020",

month = aug,

day = "1",

doi = "10.1016/j.cattod.2019.11.014",

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T1 - Low-temperature oxidative coupling of methane using alkaline earth metal oxide-supported perovskites

AU - Lim, Seoyeon

AU - Choi, Jae Wook

AU - Jin Suh, Dong

AU - Lee, Ung

AU - Song, Kwang Ho

AU - Ha, Jeong Myeong

N1 - Funding Information: This work was supported by C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT . ( 2015M3D3A1A01064900 ). Appendix A Funding Information: This work was supported by C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT. (2015M3D3A1A01064900). Publisher Copyright: © 2019 Elsevier B.V.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Perovskite-supported alkaline-earth metal oxide catalysts were prepared for application in the oxidative coupling of methane (OCM). The selective production of C2+ compounds, including ethane, ethylene, acetylene, propane, and propylene, was observed at reaction temperatures < 700 °C. This lower reaction temperature was not achieved with pure perovskites but only with the combination of alkaline-earth metal oxides and perovskite supports. The formation of complex mixed oxides, such as Ba-Ca-Ti-Ox, Ba-Sr-Ti-Ox, and Ba2TiO4, was also observed for these catalysts. This contributed to the improved C2+ yield at the lower reaction temperature. The strong basicity, which contributes to the improved OCM activity, was also observed for these catalysts.

AB - Perovskite-supported alkaline-earth metal oxide catalysts were prepared for application in the oxidative coupling of methane (OCM). The selective production of C2+ compounds, including ethane, ethylene, acetylene, propane, and propylene, was observed at reaction temperatures < 700 °C. This lower reaction temperature was not achieved with pure perovskites but only with the combination of alkaline-earth metal oxides and perovskite supports. The formation of complex mixed oxides, such as Ba-Ca-Ti-Ox, Ba-Sr-Ti-Ox, and Ba2TiO4, was also observed for these catalysts. This contributed to the improved C2+ yield at the lower reaction temperature. The strong basicity, which contributes to the improved OCM activity, was also observed for these catalysts.

KW - Alkaline-earth metal oxide

KW - Barium oxide

KW - Low temperature

KW - Methane

KW - Oxidative coupling

KW - Perovskite

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DO - 10.1016/j.cattod.2019.11.014

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SN - 0920-5861

VL - 352

SP - 127

EP - 133

JO - Catalysis Today

JF - Catalysis Today

ER -

Low-temperature oxidative coupling of methane using alkaline earth metal oxide-supported perovskites

Abstract

Keywords

ASJC Scopus subject areas

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