Low-temperature sintering and microwave dielectric properties of BaO·(Nd1-xBix)2O 3·4TiO2 by the glass additions

In Sun Cho; Dong Wan Kim; Jeong Ryeol Kim; Kug Sun Hong

doi:10.1016/j.ceramint.2003.12.035

Low-temperature sintering and microwave dielectric properties of BaO·(Nd_1-xBi_x)₂O ₃·4TiO₂ by the glass additions

In Sun Cho, Dong Wan Kim, Jeong Ryeol Kim, Kug Sun Hong

Research output: Contribution to journal › Conference article › peer-review

66 Citations (Scopus)

Abstract

The system BaO·(Nd_1-xBi_x)₂O ₃·4TiO₂ solid solution containing lithium borosilicate glass were prepared and examined as a low-temperature co-fired ceramics (LTCC). The sintering properties of the low-temperature sintered BaO·(Nd_1-xBi_x)₂O ₃·4TiO₂ with glass frit were investigated using dilatometer, SEM and TEM. The microwave dielectric properties were measured using a network analyzer. The addition of glass to BaO·(Nd _1-xBi_x)₂O₃·4TiO₂ significantly lowered the sintering temperature to ∼900°C in comparison to ∼1300°C for samples without glass. The formation of liquid phase present in the low temperature sintered sample was confirmed using TEM. It was found that thermal properties of the added lithium borosilicate glass dominated the sintering properties of BaO·(Nd_1-xBi_x) ₂O₃·4TiO₂ including shrinkage onset temperature and shrinkage rate. The sample of BaO·(Nd _0.8Bi_0.2)₂O₃·4TiO ₂ with 10wt.% glass sintered at 900°C exhibited a quality factor (Q×f) of 2200GHz, a ε_r of 68, and a τ_f of 55ppm/°C.

Original language	English
Pages (from-to)	1181-1185
Number of pages	5
Journal	Ceramics International
Volume	30
Issue number	7
DOIs	https://doi.org/10.1016/j.ceramint.2003.12.035
Publication status	Published - 2004
Externally published	Yes
Event	3rd Asian Meeting on Electroceramics - Singapore, Singapore Duration: 2003 Dec 7 → 2003 Dec 11

Bibliographical note

Funding Information:
This research was supported by a grant from the Center for Advanced Materials Processing(CAMP) of the 21st Century Frontier R&D program funded by the Ministry of Science and Technology, Republic of Korea.

Keywords

A. Sintering
C. Dielectric properties
D. Glass ceramics
LTCC

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Process Chemistry and Technology
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/j.ceramint.2003.12.035

Cite this

@article{7a1d7838d79147fc8abf4b0d3b38afe7,

title = "Low-temperature sintering and microwave dielectric properties of BaO·(Nd1-xBix)2O 3·4TiO2 by the glass additions",

abstract = "The system BaO·(Nd1-xBix)2O 3·4TiO2 solid solution containing lithium borosilicate glass were prepared and examined as a low-temperature co-fired ceramics (LTCC). The sintering properties of the low-temperature sintered BaO·(Nd1-xBix)2O 3·4TiO2 with glass frit were investigated using dilatometer, SEM and TEM. The microwave dielectric properties were measured using a network analyzer. The addition of glass to BaO·(Nd 1-xBix)2O3·4TiO2 significantly lowered the sintering temperature to ∼900°C in comparison to ∼1300°C for samples without glass. The formation of liquid phase present in the low temperature sintered sample was confirmed using TEM. It was found that thermal properties of the added lithium borosilicate glass dominated the sintering properties of BaO·(Nd1-xBix) 2O3·4TiO2 including shrinkage onset temperature and shrinkage rate. The sample of BaO·(Nd 0.8Bi0.2)2O3·4TiO 2 with 10wt.% glass sintered at 900°C exhibited a quality factor (Q×f) of 2200GHz, a εr of 68, and a τf of 55ppm/°C.",

keywords = "A. Sintering, C. Dielectric properties, D. Glass ceramics, LTCC",

author = "Cho, {In Sun} and Kim, {Dong Wan} and Kim, {Jeong Ryeol} and Hong, {Kug Sun}",

note = "Funding Information: This research was supported by a grant from the Center for Advanced Materials Processing(CAMP) of the 21st Century Frontier R&D program funded by the Ministry of Science and Technology, Republic of Korea.; 3rd Asian Meeting on Electroceramics ; Conference date: 07-12-2003 Through 11-12-2003",

year = "2004",

doi = "10.1016/j.ceramint.2003.12.035",

language = "English",

volume = "30",

pages = "1181--1185",

journal = "Ceramics International",

issn = "0272-8842",

publisher = "Elsevier Limited",

number = "7",

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TY - JOUR

T1 - Low-temperature sintering and microwave dielectric properties of BaO·(Nd1-xBix)2O 3·4TiO2 by the glass additions

AU - Cho, In Sun

AU - Kim, Dong Wan

AU - Kim, Jeong Ryeol

AU - Hong, Kug Sun

N1 - Funding Information: This research was supported by a grant from the Center for Advanced Materials Processing(CAMP) of the 21st Century Frontier R&D program funded by the Ministry of Science and Technology, Republic of Korea.

PY - 2004

Y1 - 2004

N2 - The system BaO·(Nd1-xBix)2O 3·4TiO2 solid solution containing lithium borosilicate glass were prepared and examined as a low-temperature co-fired ceramics (LTCC). The sintering properties of the low-temperature sintered BaO·(Nd1-xBix)2O 3·4TiO2 with glass frit were investigated using dilatometer, SEM and TEM. The microwave dielectric properties were measured using a network analyzer. The addition of glass to BaO·(Nd 1-xBix)2O3·4TiO2 significantly lowered the sintering temperature to ∼900°C in comparison to ∼1300°C for samples without glass. The formation of liquid phase present in the low temperature sintered sample was confirmed using TEM. It was found that thermal properties of the added lithium borosilicate glass dominated the sintering properties of BaO·(Nd1-xBix) 2O3·4TiO2 including shrinkage onset temperature and shrinkage rate. The sample of BaO·(Nd 0.8Bi0.2)2O3·4TiO 2 with 10wt.% glass sintered at 900°C exhibited a quality factor (Q×f) of 2200GHz, a εr of 68, and a τf of 55ppm/°C.

AB - The system BaO·(Nd1-xBix)2O 3·4TiO2 solid solution containing lithium borosilicate glass were prepared and examined as a low-temperature co-fired ceramics (LTCC). The sintering properties of the low-temperature sintered BaO·(Nd1-xBix)2O 3·4TiO2 with glass frit were investigated using dilatometer, SEM and TEM. The microwave dielectric properties were measured using a network analyzer. The addition of glass to BaO·(Nd 1-xBix)2O3·4TiO2 significantly lowered the sintering temperature to ∼900°C in comparison to ∼1300°C for samples without glass. The formation of liquid phase present in the low temperature sintered sample was confirmed using TEM. It was found that thermal properties of the added lithium borosilicate glass dominated the sintering properties of BaO·(Nd1-xBix) 2O3·4TiO2 including shrinkage onset temperature and shrinkage rate. The sample of BaO·(Nd 0.8Bi0.2)2O3·4TiO 2 with 10wt.% glass sintered at 900°C exhibited a quality factor (Q×f) of 2200GHz, a εr of 68, and a τf of 55ppm/°C.

KW - A. Sintering

KW - C. Dielectric properties

KW - D. Glass ceramics

KW - LTCC

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DO - 10.1016/j.ceramint.2003.12.035

M3 - Conference article

AN - SCOPUS:4344665189

SN - 0272-8842

VL - 30

SP - 1181

EP - 1185

JO - Ceramics International

JF - Ceramics International

IS - 7

T2 - 3rd Asian Meeting on Electroceramics

Y2 - 7 December 2003 through 11 December 2003

ER -